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多壁碳纳米管/聚芳腈复合材料作为用于微生物燃料电池应用的阳极材料。

Multiwalled carbon nanotube/polyarcylonitrile composite as anode material for microbial fuel cells application.

作者信息

Kim Sun-Il, Roh Sung-Hee

机构信息

Department of Chemical and Biochemical Engineering, Chosun University, Gwangju 501-759, Korea.

出版信息

J Nanosci Nanotechnol. 2010 May;10(5):3271-4. doi: 10.1166/jnn.2010.2347.

Abstract

A microbial fuel cell (MFC) is an electrochemical device that can directly convert the chemical energy stored in organic matter into electricity using microorganisms as a biocatalyst. The performance of multiwalled carbon nanotube (MWCNT)/polyarcylonitrile (PAN) composite modified carbon paper electrodes in two-chambered MFC was investigated. The electrocatalytic behaviors of the MWCNT/PAN composite anode were examined by using cyclic voltammetry. The MWCNT/PAN composite anode showed better electrochemical performance than that of PAN anode without MWCNT and the electricity generation of the MFC increased along with the increase of the MWCNT composite loading. The 5 wt% MWCNT/PAN composite anode has the highest electrochemical activity and its maximum power density is found to be 45 mW/m2 with acetate.

摘要

微生物燃料电池(MFC)是一种电化学装置,它可以利用微生物作为生物催化剂,将储存在有机物中的化学能直接转化为电能。研究了多壁碳纳米管(MWCNT)/聚芳腈(PAN)复合改性碳纸电极在双室MFC中的性能。采用循环伏安法研究了MWCNT/PAN复合阳极的电催化行为。MWCNT/PAN复合阳极表现出比不含MWCNT的PAN阳极更好的电化学性能,并且MFC的发电量随着MWCNT复合材料负载量的增加而增加。5 wt% 的MWCNT/PAN复合阳极具有最高的电化学活性,其以乙酸盐为底物时的最大功率密度为45 mW/m2。

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