Investigation of Antifouling Properties of Surfaces Featuring Zwitterionic α-Aminophosphonic Acid Moieties.
作者信息
Wagner Natalie, Zimmermann Phyllis, Heisig Peter, Klitsche Franziska, Maison Wolfgang, Theato Patrick
机构信息
Institute for Technical and Macromolecular Chemistry, University of Hamburg, Bundesstr. 45, D-20146, Hamburg, Germany.
Institute of Biochemistry, Pharmaceutical Biology and Microbiology, University of Hamburg, Bundesstr. 45, D-20146, Hamburg, Germany.
出版信息
Macromol Biosci. 2015 Dec;15(12):1673-8. doi: 10.1002/mabi.201500196. Epub 2015 Sep 2.
Zwitterionic thin films containing α-amino phosphonic acid moieties were successfully introduced on silicon surfaces and their antifouling properties were investigated. Initially, the substrates were modified with a hybrid polymer, composed of poly(methylsilsesquioxane) (PMSSQ) and poly(4-vinyl benzaldehyde) (PStCHO). Next, a Kabachnik-Fields post-polymerization modification (sur-KF-PMR) of the functionalized aldehyde surfaces was conducted with different amines and dialkyl phosphonates. After subsequent deprotection reaction of dialkyl phosphonates, the obtained zwitterionic surfaces were characterized by various techniques and we found excellent antifouling properties of the resulting films.
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