基于卡巴契尼克-菲尔德反应的高效多组分后聚合修饰
Efficient Multicomponent Postpolymerization Modification Based on Kabachnik-Fields Reaction.
作者信息
Kakuchi Ryohei, Theato Patrick
机构信息
Institute for Technical and Macromolecular Chemistry, University of Hamburg, Bundesstr. 45, D-20146 Hamburg, Germany.
出版信息
ACS Macro Lett. 2014 Apr 15;3(4):329-332. doi: 10.1021/mz500139c. Epub 2014 Mar 21.
A Kabachnik-Fields postpolymerization modification reaction (KF-PMR) was conducted on poly(4-vinyl benzaldehyde) (poly(St-CHO)) with amines and phosphites. Successful KF-PMR was demonstrated by precise structural analysis of the obtained polymers and kinetic investigation of the KF-PMR processes, making it a powerful tool for postpolymerization modifications that lead to α-amino phosphonates as side groups.
在聚（4-乙烯基苯甲醛）（聚（苯乙烯-CHO））上，使用胺类和亚磷酸酯进行了卡巴奇尼克-菲尔德斯后聚合修饰反应（KF-PMR）。通过对所得聚合物的精确结构分析和KF-PMR过程的动力学研究，证明了KF-PMR的成功，使其成为一种用于后聚合修饰的强大工具，该修饰可生成作为侧基的α-氨基膦酸酯。
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