Inukai Shigeki, Cruz-Silva Rodolfo, Ortiz-Medina Josue, Morelos-Gomez Aaron, Takeuchi Kenji, Hayashi Takuya, Tanioka Akihiko, Araki Takumi, Tejima Syogo, Noguchi Toru, Terrones Mauricio, Endo Morinobu
Global Aqua Innovation Center, Shinshu University; 4-17-1 Wakasato, Nagano 380-8553, Japan.
Institute of Carbon Science and Technology, Shinshu University; 4-17-1 Wakasato, Nagano 380-8553, Japan.
Sci Rep. 2015 Sep 3;5:13562. doi: 10.1038/srep13562.
Clean water obtained by desalinating sea water or by purifying wastewater, constitutes a major technological objective in the so-called water century. In this work, a high-performance reverse osmosis (RO) composite thin membrane using multi-walled carbon nanotubes (MWCNT) and aromatic polyamide (PA), was successfully prepared by interfacial polymerization. The effect of MWCNT on the chlorine resistance, antifouling and desalination performances of the nanocomposite membranes were studied. We found that a suitable amount of MWCNT in PA, 15.5 wt.%, not only improves the membrane performance in terms of flow and antifouling, but also inhibits the chlorine degradation on these membranes. Therefore, the present results clearly establish a solid foundation towards more efficient large-scale water desalination and other water treatment processes.
通过海水淡化或净化废水获得清洁水,是所谓水世纪的一项主要技术目标。在这项工作中,通过界面聚合成功制备了一种使用多壁碳纳米管(MWCNT)和芳香族聚酰胺(PA)的高性能反渗透(RO)复合薄膜。研究了MWCNT对纳米复合膜耐氯性、抗污染性和脱盐性能的影响。我们发现,PA中适量的MWCNT(15.5重量%)不仅在通量和抗污染方面提高了膜性能,而且还抑制了这些膜上的氯降解。因此,目前的结果为更高效的大规模海水淡化和其他水处理工艺奠定了坚实基础。