Ahmed Mahmoud A, Mahmoud Safwat A, Mohamed Ashraf A
Chemistry Department, Faculty of Science, Ain Shams University Cairo-11566 Egypt
Veolia Water Technologies Cairo 11835 Egypt.
RSC Adv. 2024 Jun 12;14(27):18879-18906. doi: 10.1039/d4ra01796j.
Because of its great efficiency and widespread application, reverse osmosis (RO) is a popular tool for water desalination and purification. However, traditional RO membranes have a short lifespan due to membrane fouling, deterioration, decreased salt rejection rate, and the low water flux with aging. As a result, membrane modification has received a lot of attention recently, with nanomaterials being extensively researched to improve membrane efficacy and lifespan. Herein, we present an in-depth analysis of recent advances of RO membranes modification utilizing nanomaterials. An overview of the various nanomaterials used for membrane modification, including metal oxides, zeolites, and carbon nanomaterials, is provided. The synthesis techniques and methods of integrating these nanomaterials into RO membranes are also discussed. The impacts of nanomaterial change on the performance of RO membranes are addressed. The underlying mechanisms responsible for RO membrane enhancements by nanomaterials, such as improved surface hydrophilicity, reduced membrane fouling surface repulsion and anti-adhesion properties, and enhanced structural stability, are discussed. Furthermore, the review provides a critical analysis of the challenges and limitations associated with the use of nanomaterials to modify RO membranes. Overall, this review provides valuable insights into the modification of RO membranes with nanomaterials, providing a full grasp of the benefits, challenges, and future prospects of this challenging topic.
由于其高效性和广泛应用,反渗透(RO)是水脱盐和净化的常用工具。然而,由于膜污染、劣化、盐截留率降低以及老化导致的水通量低,传统的RO膜使用寿命较短。因此,膜改性最近受到了很多关注,人们对纳米材料进行了广泛研究以提高膜的效能和使用寿命。在此,我们对利用纳米材料对RO膜进行改性的最新进展进行了深入分析。提供了用于膜改性的各种纳米材料的概述,包括金属氧化物、沸石和碳纳米材料。还讨论了将这些纳米材料整合到RO膜中的合成技术和方法。探讨了纳米材料变化对RO膜性能的影响。讨论了纳米材料增强RO膜的潜在机制,如改善表面亲水性、减少膜污染、表面排斥和抗粘附性能以及增强结构稳定性。此外,该综述对使用纳米材料改性RO膜相关的挑战和局限性进行了批判性分析。总体而言,本综述为纳米材料改性RO膜提供了有价值的见解,全面把握了这一具有挑战性主题的益处、挑战和未来前景。