• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

平面异质结钙钛矿太阳能电池中多长度尺度结构的演化、加工及性能洞察

Insight into Evolution, Processing and Performance of Multi-length-scale Structures in Planar Heterojunction Perovskite Solar Cells.

作者信息

Huang Yu-Ching, Tsao Cheng-Si, Cho Yi-Ju, Chen Kuan-Chen, Chiang Kai-Ming, Hsiao Sheng-Yi, Chen Chang-Wen, Su Chun-Jen, Jeng U-Ser, Lin Hao-Wu

机构信息

Institute of Nuclear Energy Research, Longtan, Taoyuan 32546, Taiwan.

Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan.

出版信息

Sci Rep. 2015 Sep 4;5:13657. doi: 10.1038/srep13657.

DOI:10.1038/srep13657
PMID:26338280
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4559897/
Abstract

The structural characterization correlated to the processing control of hierarchical structure of planar heterojunction perovskite layer is still incomplete due to the limitations of conventional microscopy and X-ray diffraction. This present study performed the simultaneously grazing-incidence small-angle scattering and wide-angle scattering (GISAXS/GIWAXS) techniques to quantitatively probe the hierarchical structure of the planar heterojunction perovskite solar cells. The result is complementary to the currently microscopic study. Correlation between the crystallization behavior, crystal orientation, nano- and meso-scale internal structure and surface morphology of perovskite film as functions of various processing control parameters is reported for the first time. The structural transition from the fractal pore network to the surface fractal can be tuned by the chloride percentage. The GISAXS/GIWAXS measurement provides the comprehensive understanding of concurrent evolution of the film morphology and crystallization correlated to the high performance. The result can provide the insight into formation mechanism and rational synthesis design.

摘要

由于传统显微镜和X射线衍射的局限性，与平面异质结钙钛矿层分级结构的加工控制相关的结构表征仍不完整。本研究采用同时掠入射小角散射和广角散射（GISAXS/GIWAXS）技术来定量探测平面异质结钙钛矿太阳能电池的分级结构。该结果对当前的微观研究具有补充作用。首次报道了作为各种加工控制参数函数的钙钛矿薄膜的结晶行为、晶体取向、纳米和介观尺度内部结构以及表面形态之间的相关性。分形孔隙网络到表面分形的结构转变可以通过氯化物百分比来调节。GISAXS/GIWAXS测量提供了对与高性能相关的薄膜形态和结晶同时演变的全面理解。该结果可为形成机理和合理的合成设计提供见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/90c6b7f7f505/srep13657-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/50fb11773262/srep13657-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/b8267ecdf4fd/srep13657-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/9debb6acc7b4/srep13657-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/34afee814ff4/srep13657-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/75721e243c46/srep13657-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/5c8519e0eb3b/srep13657-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/26536410e450/srep13657-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/be56d023dbb3/srep13657-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/90c6b7f7f505/srep13657-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/50fb11773262/srep13657-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/b8267ecdf4fd/srep13657-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/9debb6acc7b4/srep13657-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/34afee814ff4/srep13657-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/75721e243c46/srep13657-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/5c8519e0eb3b/srep13657-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/26536410e450/srep13657-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/be56d023dbb3/srep13657-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31e8/4559897/90c6b7f7f505/srep13657-f9.jpg

相似文献

1
Insight into Evolution, Processing and Performance of Multi-length-scale Structures in Planar Heterojunction Perovskite Solar Cells.平面异质结钙钛矿太阳能电池中多长度尺度结构的演化、加工及性能洞察
Sci Rep. 2015 Sep 4;5:13657. doi: 10.1038/srep13657.
2
Mechanism and control of the structural evolution of a polymer solar cell from a bulk heterojunction to a thermally unstable hierarchical structure.从体相异质结到热不稳定分级结构的聚合物太阳能电池结构演变的机制和控制。
Nanoscale. 2013 Aug 21;5(16):7629-38. doi: 10.1039/c3nr00864a. Epub 2013 Jul 12.
3
The active layer morphology of organic solar cells probed with grazing incidence scattering techniques.用掠入射散射技术探测有机太阳能电池的活性层形态。
Adv Mater. 2014 Dec 10;26(46):7692-709. doi: 10.1002/adma.201304187. Epub 2014 Feb 12.
4
Formation Mechanism and Control of Perovskite Films from Solution to Crystalline Phase Studied by in Situ Synchrotron Scattering.原位同步辐射散射研究钙钛矿薄膜从溶液到晶相的形成机制和控制。
ACS Appl Mater Interfaces. 2016 Oct 12;8(40):26712-26721. doi: 10.1021/acsami.6b07468. Epub 2016 Sep 28.
5
First step into space: performance and morphological evolution of P3HT:PCBM bulk heterojunction solar cells [corrected] under AM0 illumination.首次进入太空：在 AM0 光照下 P3HT:PCBM 本体异质结太阳能电池的性能和形态演变[更正]。
ACS Appl Mater Interfaces. 2014 Oct 22;6(20):17902-10. doi: 10.1021/am504608p. Epub 2014 Oct 7.
6
Correlation between Hierarchical Structure and Processing Control of Large-area Spray-coated Polymer Solar Cells toward High Performance.大面积喷涂聚合物太阳能电池的层级结构与加工控制对高性能的相关性
Sci Rep. 2016 Jan 28;6:20062. doi: 10.1038/srep20062.
7
Quantitative nanoorganized structural evolution for a high efficiency bulk heterojunction polymer solar cell.定量纳米结构演化实现高效体异质结聚合物太阳能电池。
J Am Chem Soc. 2011 Aug 24;133(33):13064-73. doi: 10.1021/ja202977r. Epub 2011 Jul 28.
8
Evolution of lateral structures during the functional stack build-up of P3HT:PCBM-based bulk heterojunction solar cells.在基于 P3HT:PCBM 的体异质结太阳能电池的功能层堆积过程中，侧向结构的演变。
ACS Appl Mater Interfaces. 2013 Sep 11;5(17):8581-90. doi: 10.1021/am402045p. Epub 2013 Aug 27.
9
Competition between fullerene aggregation and poly(3-hexylthiophene) crystallization upon annealing of bulk heterojunction solar cells.在体异质结太阳能电池退火过程中富勒烯聚集与聚（3-己基噻吩）结晶的竞争。
ACS Nano. 2011 Aug 23;5(8):6233-43. doi: 10.1021/nn2010816. Epub 2011 Jul 18.
10
Grazing incidence wide angle x-ray scattering at the wiggler beamline BW4 of HASYLAB.在HASYLAB的摆动器光束线BW4处进行掠入射广角X射线散射。
Rev Sci Instrum. 2010 Oct;81(10):105105. doi: 10.1063/1.3488459.

引用本文的文献

1
Hot Gas-Blowing Assisted Crystallinity Management of Bar-Coated Perovskite Solar Cells and Modules.条形涂布钙钛矿太阳能电池及组件的热气吹拂辅助结晶度管理
Small Sci. 2023 Jul 18;3(9):2300069. doi: 10.1002/smsc.202300069. eCollection 2023 Sep.
2
Influence of Additives on the Crystallization Dynamics of Methyl Ammonium Lead Halide Perovskites.添加剂对甲基铵卤化铅钙钛矿结晶动力学的影响
ACS Appl Energy Mater. 2021 Feb 22;4(2):1398-1409. doi: 10.1021/acsaem.0c02625. Epub 2021 Feb 2.
3
Perovskite Crystallization Dynamics during Spin-Casting: An Wide-Angle X-ray Scattering Study.

本文引用的文献

1
Benefit of Grain Boundaries in Organic-Inorganic Halide Planar Perovskite Solar Cells.有机-无机卤化物平面钙钛矿太阳能电池中晶界的益处
J Phys Chem Lett. 2015 Mar 5;6(5):875-80. doi: 10.1021/acs.jpclett.5b00182. Epub 2015 Feb 24.
2
Planar CH3NH3PbI3 Perovskite Solar Cells with Constant 17.2% Average Power Conversion Efficiency Irrespective of the Scan Rate.平面CH3NH3PbI3钙钛矿太阳能电池，无论扫描速率如何，平均功率转换效率恒定为17.2%。
Adv Mater. 2015 Jun 10;27(22):3424-30. doi: 10.1002/adma.201500048. Epub 2015 Apr 27.
3
Efficient and uniform planar-type perovskite solar cells by simple sequential vacuum deposition.
旋涂过程中钙钛矿的结晶动力学：广角X射线散射研究
ACS Appl Energy Mater. 2020 Jul 27;3(7):6155-6164. doi: 10.1021/acsaem.9b02470. Epub 2020 Jun 16.
4
Structural evolution and mechanism of strain glass transition in TiNi shape memory alloy studied by anomalous small-angle X-ray scattering.利用反常小角X射线散射研究TiNi形状记忆合金中应变玻璃转变的结构演变及机理
Sci Rep. 2020 Jun 10;10(1):9402. doi: 10.1038/s41598-020-66396-w.
5
Radio Frequency Magnetron Sputtering Deposition of TiO2 Thin Films and Their Perovskite Solar Cell Applications.二氧化钛薄膜的射频磁控溅射沉积及其在钙钛矿太阳能电池中的应用
Sci Rep. 2015 Dec 3;5:17684. doi: 10.1038/srep17684.
高效且均匀的平面型钙钛矿太阳能电池通过简单的顺序真空沉积法制备。
Adv Mater. 2014 Oct;26(38):6647-52. doi: 10.1002/adma.201402461. Epub 2014 Sep 1.
4
Boosting the power conversion efficiency of perovskite solar cells using self-organized polymeric hole extraction layers with high work function.利用具有高功函数的自组织聚合物空穴萃取层来提高钙钛矿太阳能电池的功率转换效率。
Adv Mater. 2014 Oct 8;26(37):6461-6. doi: 10.1002/adma.201401775. Epub 2014 Aug 14.
5
Photovoltaics. Interface engineering of highly efficient perovskite solar cells.光伏。高效钙钛矿太阳能电池的界面工程。
Science. 2014 Aug 1;345(6196):542-6. doi: 10.1126/science.1254050.
6
Controllable self-induced passivation of hybrid lead iodide perovskites toward high performance solar cells.可控自诱导混合卤化铅钙钛矿的钝化实现高性能太阳能电池。
Nano Lett. 2014 Jul 9;14(7):4158-63. doi: 10.1021/nl501838y. Epub 2014 Jun 30.
7
Thermally induced structural evolution and performance of mesoporous block copolymer-directed alumina perovskite solar cells.热诱导介孔嵌段共聚物导向的氧化铝钙钛矿太阳能电池的结构演变与性能
ACS Nano. 2014 May 27;8(5):4730-9. doi: 10.1021/nn500526t. Epub 2014 Apr 11.
8
Additive enhanced crystallization of solution-processed perovskite for highly efficient planar-heterojunction solar cells.用于高效平面异质结太阳能电池的溶液法制备钙钛矿的添加剂增强结晶
Adv Mater. 2014 Jun 11;26(22):3748-54. doi: 10.1002/adma.201400231. Epub 2014 Mar 14.
9
Low-temperature solution-processed perovskite solar cells with high efficiency and flexibility.高效柔性低温溶液处理钙钛矿太阳能电池。
ACS Nano. 2014 Feb 25;8(2):1674-80. doi: 10.1021/nn406020d. Epub 2014 Jan 7.
10
Perovskite-based hybrid solar cells exceeding 10% efficiency with high reproducibility using a thin film sandwich approach.采用薄膜夹层法制备高效率、高重复性的钙钛矿基混合太阳能电池，其光电转换效率超过 10%。
Adv Mater. 2014 Apr 2;26(13):2041-6. doi: 10.1002/adma.201304803. Epub 2013 Dec 12.