ETH Zurich, Institute for Chemical and Bioengineering, Vladimir-Prelog-Weg 1, 8093 Zurich, Switzerland.
ETH Zurich, Institute for Chemical and Bioengineering, Vladimir-Prelog-Weg 1, 8093 Zurich, Switzerland; Leuphana University Lüneburg, Institute of Sustainable Chemistry and Environmental Chemistry, Scharnhorststrasse 1, 21335 Lüneburg, Germany.
Environ Pollut. 2016 Oct;217:11-8. doi: 10.1016/j.envpol.2015.08.028. Epub 2015 Sep 2.
In this work, agricultural and background soil concentrations of p,p'-DDT, p,p'-DDE, HCB, α-, β- and γ-HCH from 1993 to 2012 were collected from 73 peer-reviewed publications, and analysed statistically. For the period 2003-2012 and for all chemicals, the mean concentration in agricultural soil is significantly higher than the concentration in background soil. In addition to the statistical analysis, concentrations of p,p'-DDT and α-HCH in soils were calculated with a global environmental fate and transport model. A decrease in the mean soil concentration from the first decade to the second was observed with the model, but this decrease is not visible in the measured concentrations, which could result from ongoing use of p,p'-DDT and α-HCH Furthermore, modelled background soil concentrations are generally lower than measurements. This implies that background soil may have received p,p'-DDT and α-HCH through additional routes not described by the model such as spray drift.
本工作收集了 1993 年至 2012 年间 73 篇同行评议出版物中农业土壤和背景土壤中 p,p'-DDT、p,p'-DDE、HCB、α-、β-和 γ-HCH 的浓度数据,并进行了统计分析。对于 2003-2012 年期间以及所有化学物质,农业土壤中的平均浓度明显高于背景土壤中的浓度。除了统计分析之外,还使用全球环境归趋和传输模型计算了土壤中 p,p'-DDT 和 α-HCH 的浓度。模型显示,与第一个十年相比,第二个十年的土壤平均浓度有所下降,但在实测浓度中并未观察到这种下降,这可能是由于 p,p'-DDT 和 α-HCH 的持续使用造成的。此外,模型预测的背景土壤浓度通常低于实测值。这意味着背景土壤可能通过模型未描述的其他途径(如喷雾漂移)接收了 p,p'-DDT 和 α-HCH。