Chrysaorenes: assembling coronoid hydrocarbons via the fold-in synthesis.
作者信息
Majewski Marcin A, Lis Tadeusz, Cybińska Joanna, Stępień Marcin
机构信息
Wydział Chemii, Uniwersytet Wrocławski, ul. F. Joliot-Curie 14, 50-383 Wrocław, Poland.
出版信息
Chem Commun (Camb). 2015 Oct 21;51(82):15094-7. doi: 10.1039/c5cc06046j. Epub 2015 Sep 8.
PMID:26345548
Abstract
Two coronoid hydrocarbons, [3]- and [4]chrysaorene were synthesized from fluorenophane precursors using the fold-in strategy. [3]Chrysaorene is a bowl-shaped fragment of the C240-Ih fullerene, whereas [4]chrysaorene is planar and contains a unique large 24-membered internal ring. The chrysaorenes show geometry-dependent magnetic properties and are strongly fluorescent.
摘要
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