锑卟啉作为红光驱动的光催化剂，用于在有空气存在的情况下从卤化物溶液中生产太阳能燃料。
Antimony porphyrins as red-light powered photocatalysts for solar fuel production from halide solutions in the presence of air.
作者信息
Ertl M, Wöß E, Knör G
机构信息
Johannes Kepler University (JKU), Institute of Inorganic Chemistry, Altenbergerstr. 69, A-4040 Linz, Austria.
出版信息
Photochem Photobiol Sci. 2015 Oct;14(10):1826-30. doi: 10.1039/c5pp00238a.
PMID:26360604
Abstract
Halide ions (X(-)) as cheap and abundant electron donors are oxidized with simulated sunlight in a photocatalytic reaction based on robust antimony porphyrins acting as red-light harvesting multielectron transfer sensitizers. Besides halogen formation (X2/X3(-)) this solar energy storing process under certain conditions also accumulates hydrogen peroxide (H2O2) as a second energy-rich compound.
摘要
卤离子（X(-)）作为廉价且丰富的电子供体，在基于具有红光捕获多电子转移敏化剂功能的稳健锑卟啉的光催化反应中，被模拟太阳光氧化。除了形成卤素（X2/X3(-)）外，在某些条件下，这种太阳能存储过程还会积累过氧化氢（H2O2）作为第二种富含能量的化合物。
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