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原位合成在苎麻纤维上的贵金属纳米粒子的功能应用。

Functional Application of Noble Metal Nanoparticles In Situ Synthesized on Ramie Fibers.

机构信息

School of Textile Science and Engineering, Wuhan Textile University, Wuhan, 430073, China.

Institute for Frontier Materials, Deakin University, Geelong, VIC, 3216, Australia.

出版信息

Nanoscale Res Lett. 2015 Dec;10(1):366. doi: 10.1186/s11671-015-1074-1. Epub 2015 Sep 17.

Abstract

Different functions were imparted to ramie fibers through treatment with noble metal nanoparticles including silver and gold nanoparticles. The in situ synthesis of silver and gold nanoparticles was achieved by heating in the presence of ramie fibers in the corresponding solutions of precursors. The unique optical property of synthesized noble metal nanoparticles, i.e., localized surface plasmon resonance, endowed ramie fibers with bright colors. Color strength (K/S) of fibers increased with heating temperature. Silver nanoparticles were obtained in alkaline solution, while acidic condition was conducive to gold nanoparticles. The optical properties of treated ramie fibers were investigated using UV-vis absorption spectroscopy. Scanning electron microscopy (SEM) was employed to observe the morphologies of silver and gold nanoparticles in situ synthesized on fibers. The ramie fibers treated with noble metal nanoparticles showed remarkable catalytic activity for reduction of 4-nitrophenol (4-NP) by sodium borohydride. Moreover, the silver nanoparticle treatment showed significant antibacterial property on ramie fibers.

摘要

通过用包括银和金纳米粒子在内的贵金属纳米粒子处理,赋予了苎麻纤维不同的功能。通过在相应的前体溶液中存在苎麻纤维加热原位合成银和金纳米粒子。合成贵金属纳米粒子的独特光学性质,即局域表面等离子体共振,赋予了苎麻纤维鲜艳的颜色。纤维的色深(K/S)随加热温度的升高而增加。在碱性溶液中得到银纳米粒子,而酸性条件有利于金纳米粒子的生成。用紫外可见吸收光谱法研究了处理后的苎麻纤维的光学性质。扫描电子显微镜(SEM)用于观察原位合成在纤维上的银和金纳米粒子的形态。贵金属纳米粒子处理的苎麻纤维对硼氢化钠还原 4-硝基苯酚(4-NP)显示出显著的催化活性。此外,银纳米粒子处理对苎麻纤维表现出显著的抗菌性能。

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