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大尺寸石墨烯及钛-多壁碳纳米管/大尺寸石墨烯复合材料的制备:其光催化性能及潜在应用

Fabrication of large size graphene and Ti- MWCNTs/ large size graphene composites: their photocatalytic properties and potential application.

作者信息

Ullah Kefayat, Oh Won-Chun

机构信息

Department of Advanced Materials Science &Engineering, Hanseo University, Seosan-si, Chungnam-do, Korea, 356-706.

出版信息

Sci Rep. 2015 Sep 18;5:14242. doi: 10.1038/srep14242.

Abstract

Large size graphene (LSG) and multiwall carbon nanotubes (MWCNTs) on LSG were synthesized on a copper surface via chemical vapor deposition (CVD) at low temperature and normal pressure. The LSG were formed through an easy chemical cyclic reaction in which liquid benzene was heated to a temperature below its boiling point to create benzene vapors as graphene precursor material. The reaction mechanism was observed, and the time-dependent analysis of the reaction revealed that mounds of the carbon nanotubes had grown as a result of the island that was found on the LSG sheet. The implications of the mechanism that we have introduced were investigated by coating a titanium sheet on the MWCNTs/LSG and LSG on the semiconductor electronic device. The photonic response was observed to be markedly high, which can be attributed to the positive synergetic effect between the Ti and LSG sheet of our prepared composites.

摘要

通过低温常压化学气相沉积(CVD)在铜表面合成了大尺寸石墨烯(LSG)以及LSG上的多壁碳纳米管(MWCNTs)。LSG是通过一种简单的化学循环反应形成的,在该反应中,将液态苯加热到低于其沸点的温度,以产生作为石墨烯前驱体材料的苯蒸气。观察了反应机理,对反应的时间依赖性分析表明,由于在LSG片材上发现的岛状物,碳纳米管堆得以生长。通过在半导体电子器件上的MWCNTs/LSG和LSG上涂覆钛片,研究了我们所引入的机理的影响。观察到光子响应明显很高,这可归因于我们制备的复合材料中Ti和LSG片之间的正协同效应。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ae08/4585562/2a96d6f7d4f8/srep14242-f1.jpg

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