Marini Bettolo Marconi Umberto, Maggi Claudio
Scuola di Scienze e Tecnologie, Università di Camerino, Via Madonna delle Carceri, 62032, Camerino, INFN Perugia, Italy.
Dipartimento di Fisica, Università di Roma Sapienza, I-00185, Rome, Italy.
Soft Matter. 2015 Dec 7;11(45):8768-81. doi: 10.1039/c5sm01718a.
We present a stochastic description of a model of N mutually interacting active particles in the presence of external fields and characterize its steady state behavior in the absence of currents. To reproduce the effects of the experimentally observed persistence of the trajectories of the active particles we consider a Gaussian force having a non-vanishing correlation time τ, whose finiteness is a measure of the activity of the system. With these ingredients we show that it is possible to develop a statistical mechanical approach similar to the one employed in the study of equilibrium liquids and to obtain the explicit form of the many-particle distribution function by means of the multidimensional unified colored noise approximation. Such a distribution plays a role analogous to the Gibbs distribution in equilibrium statistical mechanics and provides complete information about the microscopic state of the system. From here we develop a method to determine the one- and two-particle distribution functions in the spirit of the Born-Green-Yvon (BGY) equations of equilibrium statistical mechanics. The resulting equations which contain extra-correlations induced by the activity allow us to determine the stationary density profiles in the presence of external fields, the pair correlations and the pressure of active fluids. In the low density regime we obtained the effective pair potential ϕ(r) acting between two isolated particles separated by a distance, r, showing the existence of an effective attraction between them induced by activity. Based on these results, in the second half of the paper we propose a mean field theory as an approach simpler than the BGY hierarchy and use it to derive a van der Waals expression of the equation of state.
我们给出了在存在外场的情况下,(N)个相互作用的活性粒子模型的随机描述,并刻画了其在无电流情况下的稳态行为。为了重现实验观察到的活性粒子轨迹的持续性效应,我们考虑一种具有非零关联时间(\tau)的高斯力,其有限性是系统活性的一种度量。利用这些要素,我们表明可以发展出一种类似于研究平衡液体时所采用的统计力学方法,并通过多维统一有色噪声近似获得多粒子分布函数的显式形式。这样的分布在平衡统计力学中起着类似于吉布斯分布的作用,并提供了关于系统微观状态的完整信息。由此我们本着平衡统计力学的玻恩 - 格林 - 伊冯(BGY)方程的精神,发展出一种确定单粒子和双粒子分布函数的方法。所得方程包含由活性引起的额外关联,这使我们能够确定在外场存在时的稳态密度分布、对关联以及活性流体的压力。在低密度区域,我们得到了作用在相距(r)的两个孤立粒子之间的有效对势(\phi(r)),表明活性在它们之间诱导出有效吸引力。基于这些结果,在论文的后半部分,我们提出一种平均场理论,作为一种比BGY层级更简单的方法,并使用它来推导状态方程的范德瓦尔斯表达式。