SMARTS, Metallurgy and Materials Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 T.N, India.
SMARTS, Metallurgy and Materials Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 T.N, India.
Adv Colloid Interface Sci. 2015 Nov;225:146-76. doi: 10.1016/j.cis.2015.08.014. Epub 2015 Sep 3.
Nanofluids are dispersions of nanomaterials (e.g. nanoparticles, nanofibers, nanotubes, nanowires, nanorods, nanosheet, or droplets) in base fluids. Nanofluids have been a topic of great interest during the last one decade primarily due to the initial reports of anomalous thermal conductivity (k) enhancement in nanofluids with a small percentage of nanoparticles. This field has been quite controversial, with multiple reports of anomalous enhancement in thermal conductivity and many other reports of the thermal conductivity increase within the classical Maxwell mixing model. Several mechanisms have been proposed for explaining the observed enhancement in thermal conductivity. The role of Brownian motion, interfacial resistance, morphology of suspended nanoparticles and aggregating behavior is investigated both experimentally and theoretically. As the understanding of specific heat capacity of nanofluids is a prerequisite for their effective utilization in heat transfer applications, it is also investigated by many researchers. From the initial focus on thermophysical properties of nanofluids, the attention is now shifted to tailoring of novel nanofluids with large thermal conductivities. Further, to overcome the limitations of traditional heat transfer media, phase change materials (PCMs) and hybrid nanofluids are being developed as effective media for thermal energy storage. This review focuses the recent progress in nanofluids research from a heat transfer perspective. Emphasis is given for the latest work on thermal properties of nanofluids, phase change materials and hybrid nanofluids. The preparation of nanofluids by various techniques, methods of stabilization, stability measurement techniques, thermal conductivity and heat capacity studies, proposed mechanisms of heat transport, theoretical models on thermal conductivity, factors influencing k and the effect of nanoinclusions in PCM are discussed in this review. Sufficient background information is also provided for the beginners.
纳米流体是纳米材料(例如纳米粒子、纳米纤维、纳米管、纳米线、纳米棒、纳米片或液滴)在基液中的分散体。在过去的十年中,纳米流体一直是一个热门话题,主要是因为最初报道了纳米流体中纳米粒子的小百分比可以显著提高热导率 (k)。这个领域一直存在很多争议,有多个关于热导率异常增强的报道,还有很多关于经典 Maxwell 混合模型内热导率增加的报道。已经提出了几种机制来解释观察到的热导率增强。布朗运动、界面电阻、悬浮纳米粒子的形态和聚集行为的作用已经在实验和理论上进行了研究。由于了解纳米流体的比热容是在传热应用中有效利用它们的前提,因此许多研究人员也对其进行了研究。从最初关注纳米流体的热物理性质,现在的注意力转移到了具有较大热导率的新型纳米流体的设计上。此外,为了克服传统传热介质的局限性,将相变材料 (PCM) 和混合纳米流体开发为有效的热能存储介质。本综述从传热的角度重点介绍了纳米流体研究的最新进展。重点介绍了纳米流体、相变材料和混合纳米流体的热物性的最新工作。综述了通过各种技术制备纳米流体、稳定方法、稳定性测量技术、热导率和比热容研究、传热的提出机制、热导率的理论模型、影响 k 的因素以及纳米颗粒在 PCM 中的作用。还为初学者提供了足够的背景信息。