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结晶紫内酯水杨醛腙锌(II)配合物:一种在溶液和固体基质中均具有可逆光致变色性能的材料。

Crystal Violet Lactone Salicylaldehyde Hydrazone Zn(II) Complex: a Reversible Photochromic Material both in Solution and in Solid Matrix.

作者信息

Li Kai, Li Yuanyuan, Tao Jing, Liu Lu, Wang Lili, Hou Hongwei, Tong Aijun

机构信息

College of Chemistry and Molecular Engineering, Zhengzhou University, Henan 450001, P. R. China.

School of Chemistry and Chemical Engineering, Henan University of Technology, Henan 450001, P. R. China.

出版信息

Sci Rep. 2015 Sep 28;5:14467. doi: 10.1038/srep14467.

Abstract

Crystal violet lactone (CVL) is a classic halochromic dye which has been widely used as chromogenic reagent in thermochromic and piezochromic systems. In this work, a very first example of CVL-based reversible photochromic compound was developed, which showed distinct color change upon UV-visible light irradiation both in solution and in solid matrix. Moreover, metal complex of CVL salicylaldehyde hydrozone was facilely synthesized, exhibiting reversible photochromic properties with good fatigue resistance. It was served as promising solid material for photo-patterning.

摘要

结晶紫内酯(CVL)是一种经典的加酸显色染料,已被广泛用作热致变色和压致变色体系中的显色剂。在这项工作中,首次开发了基于CVL的可逆光致变色化合物,该化合物在溶液和固体基质中经紫外-可见光照射后均表现出明显的颜色变化。此外,还 facilely 合成了CVL水杨醛腙金属配合物,其具有可逆光致变色性能且抗疲劳性良好。它有望作为光图案化的固体材料。

“facilely”这个词可能有误,推测可能是“easily”(容易地),这里暂且按字面翻译。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ae0/4585988/4cb02b95fe51/srep14467-f1.jpg

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