Wan Fang, Qiu Li-Xia, Zhou Liang-Liang, Sun Yan-Qiong, You Yi
College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, People's Republic of China.
Dalton Trans. 2015 Nov 14;44(42):18320-3. doi: 10.1039/c5dt03405a. Epub 2015 Oct 8.
The azide anion as an energy acceptor and an electron donor has been introduced into a metal-viologen compound to form a 2D layered viologen-based trifunctional material, which exhibits the rare discolored function of reversible photochromism and thermochromism. Interestingly, its fluorescence can be switched by visible light irradiation and heating in air.
叠氮阴离子作为能量受体和电子供体被引入到一种金属紫精化合物中,形成了一种二维层状紫精基三功能材料,该材料展现出可逆光致变色和热致变色这种罕见的变色功能。有趣的是,其荧光可通过可见光照射和在空气中加热来切换。