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多孔氮掺杂碳纳米纤维封装的锡纳米点作为用于先进钠离子电池的独立式正极。

Tin Nanodots Encapsulated in Porous Nitrogen-Doped Carbon Nanofibers as a Free-Standing Anode for Advanced Sodium-Ion Batteries.

机构信息

Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071, China.

Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin, 300071, China.

出版信息

Adv Mater. 2015 Nov;27(42):6702-7. doi: 10.1002/adma.201503015. Epub 2015 Sep 30.

DOI:10.1002/adma.201503015
PMID:26422696
Abstract

Ultrasmall Sn nanodots (1-2 nm) are homogeneously encapsulated in porous N-doped carbon nanofibers using a simple and scalable electrospinning method. The composite nanofibers weave into flexible free-standing membrane and can be directly used as binder- and current collector-free anode for Na-ion batteries, exhibiting excellent electrochemical performance with high reversible capacity, exceptional rate capability, and ultralong cycle life.

摘要

超小 Sn 纳米点(1-2nm)通过简单且可扩展的静电纺丝方法均匀地封装在多孔 N 掺杂碳纳米纤维中。该复合纳米纤维编织成柔性独立膜,可直接用作钠离子电池的无粘结剂和无集流器的阳极,表现出高可逆容量、优异倍率性能和超长循环寿命的卓越电化学性能。

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