Fu Yonghuan, Dong Yulian, Shen Yonglong, Zhao Huaping, Shao Guosheng, Lei Yong
Fachgebiet Angewandte Nanophysik, Institut für Physik & IMN MacroNano, Technische Universität Ilmenau, 98693, Ilmenau, Germany.
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, 450001, China.
Small. 2024 Dec;20(51):e2406630. doi: 10.1002/smll.202406630. Epub 2024 Oct 7.
Owing to the low potential (vs K/K), good cycling stability, and sustainability, carbon-based materials stand out as one of the optimal anode materials for potassium-ion batteries (PIBs). However, achieving high-rate performance and excellent capacity with the current carbon-based materials is challenging because of the sluggish reaction kinetics and the low capacity of carbon-based anodes. The doping of nitrogen proves to be an effective way to improve the rate performance and capacity of carbon-based materials as PIB anode. However, a review article is lacking in systematically summarizing the features and functions of nitrogen doping types. In this sense, it is necessary to provide a fundamental understanding of doped nitrogen types in nitrogen-doped(N-doped) carbon materials. The types, functions, and applications of nitrogen-doped carbon-based materials are overviewed in this review. Then, the recent advances in the synthesis, properties, and applications of N-doped carbon as both active and modification materials for PIBs anode are summarized. Finally, doped nitrogen's main features and functions are concluded, and critical perspectives for future research in this field are outlined.
由于具有低电位(相对于K/K)、良好的循环稳定性和可持续性,碳基材料成为钾离子电池(PIB)的最佳负极材料之一。然而,由于反应动力学缓慢以及碳基负极容量较低,利用当前的碳基材料实现高倍率性能和优异容量具有挑战性。氮掺杂被证明是提高碳基材料作为PIB负极的倍率性能和容量的有效方法。然而,缺乏一篇综述文章系统地总结氮掺杂类型的特征和功能。从这个意义上讲,有必要对氮掺杂(N掺杂)碳材料中的掺杂氮类型有一个基本的了解。本文综述了氮掺杂碳基材料的类型、功能和应用。然后,总结了N掺杂碳作为PIB负极的活性和改性材料在合成、性能和应用方面的最新进展。最后,总结了掺杂氮的主要特征和功能,并概述了该领域未来研究的关键观点。