Ravi Kumar D V, Woo Kyoohee, Moon Jooho
Department of Materials Science and Engineering, Yonsei University, 50 Yonsei-ro Seodaemun-gu, Seoul 120-749, Republic of Korea.
Nanoscale. 2015 Nov 7;7(41):17195-210. doi: 10.1039/c5nr05138j.
Copper nanowires (Cu NWs) are of particular interest for application as transparent and flexible conducting electrodes in 'see-through' and/or 'deformable' future electronics due to their excellent electrical, optical, and mechanical properties. It is necessary to develop reliable and facile methods to produce well-defined Cu NWs prior to their full exploitation. Among the wide variety of methods available to generate Cu NWs, solution-based synthesis routes are considered to be a promising strategy because of several advantages including fewer constraints on the selection of precursors, the solvent and reaction conditions, and the feasibility of large-scale low-cost production. Here, we provide a thorough review of various recently developed synthetic methodologies to obtain Cu NWs, with particular emphasis on wet chemical synthesis approaches including a hydrothermal route, reduction of metal precursors, and catalytic synthesis. The emerging applications of Cu NWs including transparent electrodes and flexible/stretchable electronics are also discussed, followed by brief comments on the remaining challenges and future research perspectives.
由于具有优异的电学、光学和机械性能,铜纳米线(Cu NWs)在未来的“透明”和/或“可变形”电子设备中作为透明且柔性的导电电极具有特殊的应用价值。在充分开发利用铜纳米线之前,有必要开发可靠且简便的方法来制备形貌规整的铜纳米线。在众多可用于制备铜纳米线的方法中,基于溶液的合成路线被认为是一种很有前景的策略,因为它具有诸多优点,包括对前驱体、溶剂和反应条件的选择限制较少,以及大规模低成本生产的可行性。在此,我们全面综述了各种近期开发的用于制备铜纳米线的合成方法,特别强调了湿化学合成方法,包括水热法、金属前驱体还原法和催化合成法。还讨论了铜纳米线在透明电极和柔性/可拉伸电子器件等方面的新兴应用,随后对尚存的挑战和未来的研究前景作了简要评论。