Valizadeh Rezvan, Mahdavian Leila
a Department of Chemistry , Islamic Azad University , Doroud Branch, Doroud , Lorestan Province , Iran.
Int J Phytoremediation. 2016;18(4):329-36. doi: 10.1080/15226514.2015.1094449.
In recent years, use of plants for remediation of contaminated soils, especially removal of heavy metals, is considered. The current study tends to investigate the removal of lead and nickel ions by the Convolvulus tricolor (CTC), was grown for 30 days in different concentrations of lead and nickel ions. Then concentration of them in soil and different organs of the plant was measured by atomic absorption spectrometry. The highest absorbed of them occurred in concentration 0.001N, which highest Pb(2+) accumulation is in the aerial parts of the plant: leaf > stem > root and for Ni(2)+: root > stem > leaf. No ion was observed into the flowers and nickel ion absorption is more of lead ion in different plant organs of CTC. The experimental isotherm data were investigated using isotherms of Langmuir, Freundlich, BET, Temkin and Dubinin-Radushkevich (DRK). The correlation coefficient for all of them is calculated that show the best correlation coefficient for Ni(2+) adsorption is obtained BET model, whereas for Pb(2+) adsorption in root is Freundlich model but for its leaf and stem is BET model. The results show, CTC is suitable for Pb(2+) and Ni(2+) and this technique is in-situ method, simple, and low cost.
近年来,人们考虑利用植物修复受污染土壤,尤其是去除重金属。当前研究旨在调查三色旋花(CTC)对铅离子和镍离子的去除情况,该植物在不同浓度的铅离子和镍离子中生长30天。然后通过原子吸收光谱法测量土壤和植物不同器官中它们的浓度。它们的最高吸收量出现在0.001N浓度下,其中植物地上部分铅(2+)的最高积累量为:叶>茎>根,而镍(2+)为:根>茎>叶。在花中未观察到离子,且在三色旋花的不同植物器官中镍离子的吸收量多于铅离子。使用朗缪尔、弗伦德利希、BET、坦金和杜比宁-拉杜舍维奇(DRK)等温线对实验等温线数据进行了研究。计算了所有等温线的相关系数,结果表明镍(2+)吸附的最佳相关系数由BET模型获得,而铅(2+)在根中的吸附为弗伦德利希模型,在叶和茎中的吸附为BET模型。结果表明,三色旋花适用于铅(2+)和镍(2+)的修复,且该技术是原位方法,简单且成本低。