Lindhorst A C, Haslinger S, Kühn Fritz E
Chair of Inorganic Chemistry/Molecular Catalysis, Technische Universität München (TUM), Department of Chemistry/Catalysis Research Center, Lichtenbergstr. 4, D-85747 Garching bei München, Germany.
Chem Commun (Camb). 2015 Dec 18;51(97):17193-212. doi: 10.1039/c5cc07146a.
The selective oxygenation of C-H bonds is a promising and interesting task for both academia and chemical industry. Inspired by the efficiency and selectivity of naturally occurring enzymes, iron heme and nonheme complexes have proven to be valuable candidates for the development of environmentally friendly catalysts as alternative to traditional systems. This feature article summarises developments of the last decade regarding oxygenation reactions of aliphatic and aromatic substrates with various oxidants catalysed by molecular iron complexes. With a special focus on the catalytic performance of the systems, both the potential and the limitations as well as mechanistic aspects are discussed in some detail.
对于学术界和化学工业而言，C-H键的选择性氧化都是一项前景广阔且引人关注的任务。受天然存在的酶的效率和选择性启发，铁血红素和非血红素配合物已被证明是开发环保型催化剂以替代传统体系的有价值候选物。这篇专题文章总结了过去十年中关于分子铁配合物催化脂肪族和芳香族底物与各种氧化剂发生氧化反应的进展。特别关注这些体系的催化性能，详细讨论了其潜力、局限性以及机理方面的问题。
