Bilyachenko Alexey N, Yalymov Alexey I, Korlyukov Alexander A, Long Jérôme, Larionova Joulia, Guari Yannick, Zubavichus Yan V, Trigub Alexander L, Shubina Elena S, Eremenko Igor L, Efimov Nikolay N, Levitsky Mikhail M
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str., 28, 117198 Moscow (Russia).
People's Friendship University of Russia, Miklukho-Maklay Str., 6, 117198 Moscow (Russia).
Chemistry. 2015 Dec 14;21(51):18563-5. doi: 10.1002/chem.201503635. Epub 2015 Nov 2.
A heterometallic phenylsilsesquioxane [(PhSiO1,5)22(CoO)3(NaO0.5)6]⋅(EtOH)6⋅(H2O) 1 cage architecture of Co(II) ions in a triangular topology exhibits a slow dynamic behavior in its magnetization, induced by the freezing of the spins of individual molecules.
一种异金属苯基倍半硅氧烷[(PhSiO₁.₅)₂₂(CoO)₃(NaO₀.₅)₆]⋅(EtOH)₆⋅(H₂O)₁，其钴(II)离子呈三角形拓扑结构的笼状架构，由于单个分子自旋的冻结，在磁化过程中表现出缓慢的动力学行为。
