A.N.Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilov str., 28, 119991 Moscow, Russia.
Dalton Trans. 2018 May 22;47(20):6893-6897. doi: 10.1039/c8dt00900g.
The first Ni(ii)-based metallagermaniumsesquioxane cage compound [(PhGeO1.5)10(NiO)4(NaO0.5)2] presents a sandwich-like structure where two germsesquioxane cages are linked through an {NiO}4 core and exhibits slow dynamics of the magnetization.
首例 Ni(ii)-基笼型锗倍半氧烷化合物 [(PhGeO1.5)10(NiO)4(NaO0.5)2] 呈现三明治状结构,其中两个锗倍半氧烷笼通过 {NiO}4 核连接,并表现出缓慢的磁化动力学。