Wang Ziyu, Liu Jingying, Xu Zai-Quan, Xue Yunzhou, Jiang Liangcong, Song Jingchao, Huang Fuzhi, Wang Yusheng, Zhong Yu Lin, Zhang Yupeng, Cheng Yi-Bing, Bao Qiaoliang
Department of Materials Science and Engineering, Faculty of Engineering, Monash University, Clayton 3800 Victoria, Australia.
Department of Materials Science and Engineering, Faculty of Engineering, Monash University, Clayton 3800 Victoria, Australia and Institute of Functional Nano and Soft Material (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215123, P. R China.
Nanoscale. 2016 Mar 28;8(12):6258-64. doi: 10.1039/c5nr06262d.
Hybrid organic-inorganic perovskites have emerged as new photovoltaic materials with impressively high power conversion efficiency due to their high optical absorption coefficient and long charge carrier diffusion length. In addition to high photoluminescence quantum efficiency and chemical tunability, hybrid organic-inorganic perovskites also show intriguing potential for diverse photonic applications. In this work, we demonstrate that polycrystalline organic-inorganic perovskite microwires can function as active optical waveguides with small propagation loss. The successful production of high quality perovskite microwires with different halogen elements enables the guiding of light with different colours. Furthermore, it is interesting to find that out-coupled light intensity from the microwire can be effectively modulated by an external electric field, which behaves as an electro-optical modulator. This finding suggests the promising applications of perovskite microwires as effective building blocks in micro/nano scale photonic circuits.
有机-无机杂化钙钛矿已成为新型光伏材料,因其具有高光学吸收系数和长电荷载流子扩散长度,展现出令人印象深刻的高功率转换效率。除了高光致发光量子效率和化学可调控性外,有机-无机杂化钙钛矿在多种光子应用方面也显示出诱人的潜力。在这项工作中,我们证明了多晶有机-无机钙钛矿微线可作为具有小传播损耗的有源光波导。成功制备出含有不同卤素元素的高质量钙钛矿微线,能够实现不同颜色光的传导。此外,有趣的是发现微线的外耦合光强度可被外部电场有效调制,其表现如同电光调制器。这一发现表明钙钛矿微线作为微/纳米尺度光子电路中有效的构建模块具有广阔的应用前景。