一氧化碳介导的铂或钯准单层在金表面的化学沉积，对碱性介质中的乙醇氧化具有优异的电催化性能。
Carbon monoxide mediated chemical deposition of Pt or Pd quasi-monolayer on Au surfaces with superior electrocatalysis for ethanol oxidation in alkaline media.
作者信息
Wang Han, Jiang Kun, Chen Qiaoli, Xie Zhaoxiong, Cai Wen-Bin
机构信息
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai 200433, China.
出版信息
Chem Commun (Camb). 2016 Jan 7;52(2):374-7. doi: 10.1039/c5cc06551h. Epub 2015 Nov 2.
PMID:26523296
Abstract
Electroless deposition of a quasi-monolayer (q-ML) of Pt and/or Pd on different Au substrates is achieved by using CO as both reducing and quenching agents, imparting Au@Pt/C or Au@Pd/C with superior electrocatalytic activity for ethanol oxidation in alkaline media.
摘要
通过使用一氧化碳作为还原剂和猝灭剂，在不同的金基底上实现了铂和/或钯的准单层（q-ML）化学沉积，赋予Au@Pt/C或Au@Pd/C在碱性介质中对乙醇氧化具有优异的电催化活性。
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