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具有 3D 互锁几何结构的非富勒烯小分子受体,实现高效有机太阳能电池。

A Nonfullerene Small Molecule Acceptor with 3D Interlocking Geometry Enabling Efficient Organic Solar Cells.

机构信息

Department of Chemical Engineering, Pohang University of Science and Technology, Pohang, 790-784, South Korea.

出版信息

Adv Mater. 2016 Jan 6;28(1):69-76. doi: 10.1002/adma.201504010. Epub 2015 Nov 5.

DOI:10.1002/adma.201504010
PMID:26539752
Abstract

A new 3D nonfullerene small-molecule acceptor is reported. The 3D interlocking geometry of the small-molecule acceptor enables uniform molecular conformation and strong intermolecular connectivity, facilitating favorable nanoscale phase separation and electron charge transfer. By employing both a novel polymer donor and a nonfullerene small-molecule acceptor in the solution-processed organic solar cells, a high-power conversion efficiency of close to 6% is demonstrated.

摘要

本文报道了一种新型 3D 非富勒烯小分子受体。该小分子受体的 3D 互锁几何形状可实现均匀的分子构象和强的分子间连接性,有利于形成有利的纳米相分离和电子电荷转移。通过在溶液处理的有机太阳能电池中采用新型聚合物给体和非富勒烯小分子受体,实现了接近 6%的高效率功率转换。

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