Shin S E, Choi H J, Hwang J Y, Bae D H
Department of Materials Science and Engineering, Yonsei University, Seoul 120-749, Korea.
School of Advanced Materials Engineering, Kookmin University, Seoul 136-702, Korea.
Sci Rep. 2015 Nov 6;5:16114. doi: 10.1038/srep16114.
Nanocomposites reinforced with nano-scale reinforcements exhibit excellent mechanical properties with low volume fraction of the reinforcement. For instance, only an addition of 0.7 vol.% few-layer graphene (FLG) into the pure titanium shows strength of ~1.5 GPa, obviously much superior to that of the monolithic titanium. The strengthening efficiency of composites is determined by several factors such as reinforcement geometrical/spatial characteristics and interfacial features between the matrix and the reinforcement. For the metal-matrix nanocomposites (MMNCs), since the nano-scale reinforcement has significantly high specific surface area, interfacial feature is more important and has to be clearly evaluated in understanding property of MMNCs. Although many researchers suggested the theoretical work using continuum mechanics in order to estimate the mechanical properties of the metallic composites, a clear determination has yet not to be proven by systematic experimental works. Here, we provide a new model to predict strength and stiffness of MMNCs based on quantitative analysis of efficiency parameters in which interface feature is strongly emphasized. To validate the model, we select multi-walled carbon nanotube (MWCNT) and FLG for reinforcement, and titanium (Ti) and aluminum (Al) for the matrix to modify bonding strength and specific surface area in the MMNCs.
用纳米级增强材料增强的纳米复合材料在增强材料体积分数较低的情况下表现出优异的力学性能。例如,仅向纯钛中添加0.7体积%的少层石墨烯(FLG)就能使强度达到约1.5 GPa,明显优于整块钛。复合材料的强化效率由几个因素决定,如增强材料的几何/空间特性以及基体与增强材料之间的界面特征。对于金属基纳米复合材料(MMNCs),由于纳米级增强材料具有显著高的比表面积,界面特征更为重要,并且在理解MMNCs的性能时必须进行清晰的评估。尽管许多研究人员提出了使用连续介质力学的理论工作来估计金属复合材料的力学性能,但尚未通过系统的实验工作得到明确的证实。在此,我们基于对效率参数的定量分析提供了一个预测MMNCs强度和刚度的新模型,其中强烈强调了界面特征。为了验证该模型,我们选择多壁碳纳米管(MWCNT)和FLG作为增强材料,选择钛(Ti)和铝(Al)作为基体,以改变MMNCs中的结合强度和比表面积。