School of Mechanical Engineering, Jiangnan University, Wuxi 214122, China.
Special Equipment Safety Supervision Inspection Institute of Jiangsu Province, National Graphene Products Quality Inspection and Testing Center (Jiangsu), Wuxi 214174, China.
Int J Mol Sci. 2022 May 30;23(11):6134. doi: 10.3390/ijms23116134.
Titanium matrix composites (TMCs) with excellent mechanical properties, reinforced by graphene, is deemed the lightweight and high strength structural materials. In this study, TC11 titanium alloy powder and graphene nanosheets (GNPs) were used as raw materials, and the composite powder with good uniformity and fluidity was obtained through non-interventional homogeneous mixing by a planetary mixer. The microstructure and mechanical properties of the GNPs-TC11 composites and TC11 alloy were compared. The results showed that the microstructure of TC11 and the composites was acicular martensite α' phase under the process parameters of 280 W laser power, 1200 mm/s scanning speed, and 0.1 mm hatch spacing. The GNPs in addition, in the composites, reduced the acicular martensite particle size and expanded the proportion of low-angle grain boundaries. The tensile strength and percentage elongation after the fracture of the TC11 titanium alloy were 1265 MPa and 4.3%, respectively. Because of addition of the GNPs, the strength and percentage elongation after the fracture of the composite increased to 1384 MPa and 8.1%, respectively, at a GNPs mass content of 0.2%. The enhancement of mechanical properties can be attributed to grain refinement, dislocation strengthening, Orowan strengthening, and load transfer strengthening.
钛基复合材料(TMCs)具有优异的机械性能,通过石墨烯增强,被认为是轻量级和高强度的结构材料。在本研究中,使用 TC11 钛合金粉末和石墨烯纳米片(GNPs)作为原材料,通过行星式混合机进行非介入式均匀混合,获得了均匀性和流动性良好的复合粉末。比较了 GNPs-TC11 复合材料和 TC11 合金的微观结构和力学性能。结果表明,在 280 W 激光功率、1200mm/s 扫描速度和 0.1mm 道间距工艺参数下,TC11 和复合材料的微观结构为针状马氏体α'相。此外,GNPs 在复合材料中减少了针状马氏体的粒径,并扩大了小角度晶界的比例。TC11 钛合金的拉伸强度和断裂后的伸长率分别为 1265MPa 和 4.3%。由于添加了 GNPs,复合材料的强度和断裂后的伸长率分别提高到 1384MPa 和 8.1%,GNPs 的质量含量为 0.2%。力学性能的提高可归因于晶粒细化、位错强化、Orowan 强化和载荷传递强化。