基于三蝶烯的大环三环主体与质子化的4,4'-联吡啶鎓/吡啶鎓盐的酸碱可控络合作用
Acid/base controllable complexation of a triptycene-derived macrotricyclic host and protonated 4,4'-bipyridinium/pyridinium salts.
作者信息
Han Ying, Meng Zheng, Chen Chuan-Feng
机构信息
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
出版信息
Chem Commun (Camb). 2016 Jan 11;52(3):590-3. doi: 10.1039/c5cc08166a. Epub 2015 Nov 9.
PMID:26548779
Abstract
A new acid/base controllable host-guest system based on a triptycene-derived macrotricyclic host and protonated 4,4'-bipyridinium/pyridinium salts was developed. Moreover, the competition complexation process between the host and two different kinds of 4,4'-bipyridinium salts could also be chemically controlled by acid and base.
摘要
基于三蝶烯衍生的大环三环主体和质子化的4,4'-联吡啶鎓/吡啶鎓盐开发了一种新型的酸碱可控主客体体系。此外，主体与两种不同的4,4'-联吡啶鎓盐之间的竞争络合过程也可以通过酸和碱进行化学控制。
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