糖基化金属酞菁
Glycosylated Metal Phthalocyanines.
作者信息
Hanack Michael
机构信息
Institut für Organische Chemie der, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany.
出版信息
Molecules. 2015 Nov 10;20(11):20173-85. doi: 10.3390/molecules201119683.
In the first part; the syntheses of mono-; di-; and tetra-glycosylated phthalonitriles is described; which are the most used starting materials for the preparation of the corresponding glycosylated metal (mostly zinc) phthalocyanines. In the second section; the preparation of symmetric and unsymmetric mono-; tetra-; and octa- glycosylated zinc phthalocyanines are reviewed; in which the sugar is attached to the phthalocyanine macrocycle; either anomerically or via another one of its OH-groups.
在第一部分中，描述了单糖基化、二糖基化和四糖基化邻苯二甲腈的合成，它们是制备相应糖基化金属（主要是锌）酞菁最常用的起始原料。在第二部分中，综述了对称和不对称的单糖基化、四糖基化和八糖基化锌酞菁的制备，其中糖以异头形式或通过其另一个羟基连接到酞菁大环上。
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