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不同固溶处理条件下电弧增材制造CoCrW合金的微观结构、力学性能及金属释放

Microstructure, mechanical property and metal release of As-SLM CoCrW alloy under different solution treatment conditions.

作者信息

Lu Yanjin, Wu Songquan, Gan Yiliang, Zhang Shuyuan, Guo Sai, Lin Junjie, Lin Jinxin

机构信息

Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, China.

Institute of Metal Research, Chinese Academy of Sciences, China.

出版信息

J Mech Behav Biomed Mater. 2015 Mar;55:179-190. doi: 10.1016/j.jmbbm.2015.10.019. Epub 2015 Nov 10.

Abstract

In the study, the microstructure, mechanical property and metal release behavior of selective laser melted CoCrW alloys under different solution treatment conditions were systemically investigated to assess their potential use in orthopedic implants. The effects of the solution treatment on the microstructure, mechanical properties and metal release were systematically studied by OM, SEM, XRD, tensile test, and ICP-AES, respectively. The XRD indicated that during the solution treatment the alloy underwent the transformation of γ-fcc to ε-hcp phase; the ε-hcp phase nearly dominated in the alloy when treated at 1200°C following the water quenching; the results from OM, SEM showed that the microstructural change was occurred under different solution treatments; solution at 1150°C with furnace cooling contributed to the formation of larger precipitates at the grain boundary regions, while the size and number of the precipitates was decreased as heated above 1100°C with the water quenching; moreover, the diamond-like structure was invisible at higher solution temperature over 1150°C following water quenching; compared with the furnace cooling, the alloy quenched by water showed excellent mechanical properties and low amount of metal release; as the alloy heated at 1200°C, the mechanical properties of the alloy reached their optimum combination at UTS=1113.6MPa, 0.2%YS=639.5MPa, and E%=20.1%, whilst showed the lower total quantity of metal release. It is suggested that a proper solution treatment is an efficient strategy for improving the mechanical properties and corrosion resistance of As-SLM CoCrW alloy that show acceptable tensile ductility.

摘要

在该研究中,系统地研究了不同固溶处理条件下选择性激光熔化CoCrW合金的微观结构、力学性能和金属释放行为,以评估其在骨科植入物中的潜在用途。分别通过光学显微镜(OM)、扫描电子显微镜(SEM)、X射线衍射(XRD)、拉伸试验和电感耦合等离子体发射光谱法(ICP - AES),系统地研究了固溶处理对微观结构、力学性能和金属释放的影响。XRD表明,在固溶处理过程中,合金经历了从γ - 面心立方到ε - 六方密堆积相的转变;水淬后在1200°C处理时,ε - 六方密堆积相在合金中几乎占主导地位;OM和SEM的结果表明,在不同的固溶处理下微观结构发生了变化;1150°C炉冷处理有助于在晶界区域形成更大的析出物,而当加热到1100°C以上水淬时,析出物的尺寸和数量减少;此外,水淬后在高于1150°C的较高固溶温度下,类金刚石结构不可见;与炉冷相比,水淬合金表现出优异的力学性能和较低的金属释放量;当合金在1200°C加热时,合金的力学性能在抗拉强度(UTS)=1113.6MPa、0.2%屈服强度(0.2%YS)=639.5MPa和伸长率(E%)=20.1%时达到最佳组合,同时金属释放总量较低。研究表明,适当的固溶处理是提高具有可接受拉伸延展性的选择性激光熔化CoCrW合金力学性能和耐腐蚀性的有效策略。

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