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[青藏高原雪坑中溶解有机碳的浓度与来源]

[Concentration and Source of Dissolved Organic Carbon in Snowpits of the Tibetan Plateau].

作者信息

Yan Fang-ping, Kang Shi-chang, Chen Peng-fei, Bai Jian-kun, Li Yang, Hu Zhao-fu, Li Chao-liu

出版信息

Huan Jing Ke Xue. 2015 Aug;36(8):2827-32.

Abstract

Snowpit samples of three glaciers (Laohugou NO. 12 Glacier (LHG), Small Dongkemadi Glacier on Mount Tanggula (TGL) and East Ronghuk Glacier on Mount Everest (ZF)) in the Tibetan Plateau were collected. Concentrations of DOC and major ions were analyzed. The results showed that average DOC concentrations of the snowpits of LHG, TGL and ZF were (250.30 +/- 157.10), (216.92 +/- 142.82) and (152.50 +/- 56.11) microg x L(-1), respectively. DOC of TGL and ZF accounted for large parts of total values of DOC and ions. Correspondingly, DOC of LHG accounted for small part (only 5%), because LHG was located at north China and intensively influenced by natural mineral dust, which caused high concentrations of Ca2+ (the highest value could reach 5299.18 microg x L(-1)) and consequently low percentage of DOC of snowpit samples. Correlation and PCA analyses were used to study the sources of DOC. DOC was significantly correlated with Ca2+, Mg2+, K+ and SO4(2-). Additionally, PCA further indicated that the main potential source of DOC was the natural source of mineral dust. Meanwhile, anthropogenic pollutants (e.g., biomass, fossil combustion and agricultural related pollutants) could also not be ignored. Moreover, the carbon depositional fluxes of three snowpits were roughly estimated, and the values of LHG, TGL and ZF snowpits were 189.23, 132.76 and 128.44 mg (m2 x a)(-1), respectively, which played a significant role in the carbon cycle in this region and was also helpful for the study of glaciers fluctuation.

摘要

采集了青藏高原三条冰川(老虎沟12号冰川(LHG)、唐古拉山小冬克玛底冰川(TGL)和珠穆朗玛峰东绒布冰川(ZF))的雪坑样本。分析了溶解性有机碳(DOC)和主要离子的浓度。结果表明,LHG、TGL和ZF雪坑的平均DOC浓度分别为(250.30±157.10)、(216.92±142.82)和(152.50±56.11)μg·L⁻¹。TGL和ZF的DOC占DOC和离子总值的很大部分。相应地,LHG的DOC占比小(仅5%),因为LHG位于中国北方,受天然矿物粉尘的强烈影响,导致Ca²⁺浓度高(最高值可达5299.18μg·L⁻¹),因此雪坑样本中DOC的百分比低。采用相关性分析和主成分分析(PCA)研究DOC的来源。DOC与Ca²⁺、Mg²⁺、K⁺和SO₄²⁻显著相关。此外,PCA进一步表明,DOC的主要潜在来源是矿物粉尘的天然来源。同时,人为污染物(如生物质、化石燃烧和农业相关污染物)也不容忽视。此外,大致估算了三个雪坑的碳沉积通量,LHG、TGL和ZF雪坑的值分别为189.23、132.76和128.44mg·(m²·a)⁻¹,这在该地区的碳循环中起着重要作用,也有助于研究冰川波动。

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