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作为电子受体的π-扩展刚性三蝶烯-三芳甲酰亚胺咪唑

π-Extended rigid triptycene-trisaroylenimidazoles as electron acceptors.

作者信息

Menke Elisabeth H, Lami Vincent, Vaynzof Yana, Mastalerz Michael

机构信息

Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 273, 69120 Heidelberg, Germany.

Kirchhoff-Institut für Physik, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 227, 69120 Heidelberg, Germany and Centre for Advanced Materials, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 225, 69120 Heidelberg, Germany.

出版信息

Chem Commun (Camb). 2016 Jan 18;52(5):1048-51. doi: 10.1039/c5cc07238g.

DOI:10.1039/c5cc07238g
PMID:26595168
Abstract

Two soluble isomeric acceptor molecules based on a triptycene core, which is connected to three aroylenimidazole units are described. Due to the inherent threefold axis, the molecules are soluble and thus could be fully photophysically characterized in solution and film. Additionally, the preliminary results of these acceptors in organic photovoltaic devices with two different donor materials are reported.

摘要

描述了两种基于三蝶烯核心的可溶性同分异构受体分子,该核心与三个芳酰亚胺咪唑单元相连。由于其固有的三重轴,这些分子具有溶解性,因此可以在溶液和薄膜中对其光物理性质进行全面表征。此外,还报道了这些受体在与两种不同供体材料组成的有机光伏器件中的初步结果。

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