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有机材料中的吉布斯-居里-沃夫定理:表面能与晶体生长关系的案例研究。

Gibbs-Curie-Wulff Theorem in Organic Materials: A Case Study on the Relationship between Surface Energy and Crystal Growth.

机构信息

Department of Chemistry, School of Science, Tianjin University and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China.

Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.

出版信息

Adv Mater. 2016 Feb 24;28(8):1697-702. doi: 10.1002/adma.201504370. Epub 2015 Dec 17.

Abstract

The equilibrium crystal shape and shape evolution of organic crystals are found to follow the Gibbs-Curie-Wulff theorem. Organic crystals are grown by the physical vapor transport technique and exhibit exactly the same shape as predicted by the Gibbs-Curie-Wulff theorem under optimal conditions. This accordance provides concrete proof for the theorem.

摘要

有机晶体的平衡晶体形状和形状演变被发现遵循吉布斯-居里-沃夫定律。有机晶体是通过物理气相传输技术生长的,在最佳条件下,其形状与吉布斯-居里-沃夫定律所预测的完全一致。这种一致性为该定律提供了具体的证据。

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