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由金属有机框架和二维材料组成的新型复合材料的制备及应用

Preparation and applications of novel composites composed of metal-organic frameworks and two-dimensional materials.

作者信息

Li Shaozhou, Yang Kai, Tan Chaoliang, Huang Xiao, Huang Wei, Zhang Hua

机构信息

Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials, Jiangsu National Synergistic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China.

出版信息

Chem Commun (Camb). 2016 Jan 28;52(8):1555-62. doi: 10.1039/c5cc09127f. Epub 2015 Dec 21.

DOI:10.1039/c5cc09127f
PMID:26686558
Abstract

Metal-organic frameworks (MOFs), an emerging type of porous crystalline materials, have received increasing attention in recent years due to their compositional, structural and chemical versatility. Moreover, great progress has been made in the fundamental study and technological development of two-dimensional (2D) materials, such as graphene and metal dichalcogenide nanosheets, which exhibit a number of unique and attractive properties for wide applications. Recently, the smart integration of the aforementioned two types of functional materials, i.e. MOFs and 2D materials, has led to improved performance in molecular absorption, separation and storage, and shown promise in selective catalysis and biosensing. This feature article aims at providing a brief introduction to the composites composed of MOFs and 2D materials, focusing mainly on their preparation methods and applications. Finally, technical challenges and future opportunities in this field will also be discussed.

摘要

金属有机框架材料(MOFs)是一种新兴的多孔晶体材料,近年来因其组成、结构和化学性质的多样性而受到越来越多的关注。此外,二维(2D)材料,如石墨烯和金属二硫属化物纳米片,在基础研究和技术开发方面取得了巨大进展,这些材料具有许多独特且吸引人的特性,可广泛应用。最近,上述两种功能材料,即MOFs和2D材料的智能整合,已在分子吸收、分离和存储方面带来了性能提升,并在选择性催化和生物传感方面展现出前景。这篇专题文章旨在简要介绍由MOFs和2D材料组成的复合材料,主要关注其制备方法和应用。最后,还将讨论该领域的技术挑战和未来机遇。

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