Dartmouth College, Chemistry, 41 College Street, Burke Laboratories, Hanover, New Hampshire, USA.
Chem Commun (Camb). 2018 Jul 12;54(57):7873-7891. doi: 10.1039/c8cc02871k.
Two-dimensional (2D) conductive metal-organic frameworks (MOFs) have emerged as a unique class of multifunctional materials due to their compositional and structural diversity accessible through bottom-up self-assembly. This feature article summarizes the progress in the development of 2D conductive MOFs with emphasis on synthetic modularity, device integration strategies, and multifunctional properties. Applications spanning sensing, catalysis, electronics, energy conversion, and storage are discussed. The challenges and future outlook in the context of molecular engineering and practical development of 2D conductive MOFs are addressed.
二维(2D)导电金属-有机骨架(MOFs)由于通过自下而上的自组装获得的组成和结构多样性,已成为一类独特的多功能材料。本文总结了二维导电 MOFs 的发展进展,重点介绍了合成的模块化、器件集成策略和多功能特性。讨论了从传感、催化、电子、能量转换和存储等多个应用领域。并讨论了在分子工程和二维导电 MOFs 的实际开发方面面临的挑战和未来展望。