Camilleri-Rumbau M S, Masse L, Dubreuil J, Mondor M, Christensen K V, Norddahl B
a Dairy and Swine Research and Development Centre , Agriculture and Agri-Food Canada , Sherbrooke , Canada.
b Department of Chemical Engineering, Biotechnology and Environmental Technology , University of Southern Denmark , Odense M , Denmark.
Environ Technol. 2016;37(13):1704-15. doi: 10.1080/09593330.2015.1128002. Epub 2016 Feb 5.
Swine manure is a valuable source of nitrogen, phosphorus and potassium. After solid-liquid separation, the resulting swine wastewater can be concentrated by reverse osmosis (RO) to produce a nitrogen-potassium rich fertilizer. However, swine wastewater has a high fouling potential and an efficient cleaning strategy is required. In this study, a semi-commercial farm scale RO spiral-wound membrane unit was fouled while processing larger volumes of swine wastewater during realistic cyclic operations over a 9-week period. Membrane cleaning was performed daily. Three different cleaning solutions, containing SDS, SDS+EDTA and NaOH were compared. About 99% of the fouling resistance could be removed by rinsing the membrane with water. Flux recoveries (FRs) above 98% were achieved for all the three cleaning solutions after cleaning. No significant differences in FR were found between the cleaning solutions. The NaOH solution thus is a good economical option for cleaning RO spiral-wound membranes fouled with swine wastewater. Soaking the membrane for 3 days in permeate water at the end of each week further improved the FR. Furthermore, a fouling resistance model for predicting the fouling rate, permeate flux decay and cleaning cycle periods based on processing time and swine wastewater conductivity was developed.
猪粪是氮、磷和钾的宝贵来源。经过固液分离后,产生的猪废水可通过反渗透(RO)进行浓缩,以生产富含氮钾的肥料。然而,猪废水具有很高的污染潜力,需要一种有效的清洗策略。在本研究中,一个半商业农场规模的RO螺旋缠绕膜装置在9周的实际循环操作中处理大量猪废水时被污染。每天进行膜清洗。比较了三种不同的清洗溶液,分别含有十二烷基硫酸钠(SDS)、SDS + 乙二胺四乙酸(EDTA)和氢氧化钠(NaOH)。用水冲洗膜可去除约99%的抗污染性。清洗后,所有三种清洗溶液的通量回收率(FRs)均达到98%以上。清洗溶液之间的FR没有显著差异。因此,NaOH溶液是清洗被猪废水污染的RO螺旋缠绕膜的一种经济有效的选择。在每周结束时将膜在渗透水中浸泡3天可进一步提高FR。此外,还建立了一个基于处理时间和猪废水电导率来预测污染速率、渗透通量衰减和清洗周期的抗污染模型。