Rh2(II)-催化吲哚形成的机理：催化剂不控制产物选择性。
Mechanism of Rh2(II)-Catalyzed Indole Formation: The Catalyst Does Not Control Product Selectivity.
机构信息
Department of Chemistry, University of California-Davis , 1 Shields Avenue, Davis, California 95616, United States.
Department of Chemistry, University of Illinois at Chicago , 845 West Taylor Street, Chicago, Illinois 60607-7061, United States.
出版信息
J Am Chem Soc. 2016 Jan 20;138(2):487-90. doi: 10.1021/jacs.5b11427. Epub 2016 Jan 8.
PMID:26718908
Abstract
Possible mechanisms for Rh-promoted indole formation from vinyl/azidoarenes were examined computationally, and a mechanism is proposed in which the Rh catalyst promotes generation of a nitrene but is not directly involved in cyclization.
摘要
从乙烯基/叠氮芳烃合成 Rh 促进的吲哚可能的机制进行了计算研究，提出了一种机制，其中 Rh 催化剂促进氮烯的生成，但不直接参与环化。
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