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用于锂氧电池的无粘结剂阴极——泡沫镍上的对苯二酚树脂诱导碳纳米管

Hydroquinone Resin Induced Carbon Nanotubes on Ni Foam As Binder-Free Cathode for Li-O2 Batteries.

作者信息

Zhu Qian-Cheng, Du Fei-Hu, Xu Shu-Mao, Wang Zong-Kai, Wang Kai-Xue, Chen Jie-Sheng

机构信息

Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University , Shanghai 200240, P. R. China.

出版信息

ACS Appl Mater Interfaces. 2016 Feb 17;8(6):3868-73. doi: 10.1021/acsami.5b10669. Epub 2016 Feb 4.

Abstract

In this work, hydroquinone resin was used to grow carbon nanotubes directly on Ni foam. The composites were obtained via a simple carbonization method, which avoids using the explosive gaseous carbon precursors that are usually applied in the chemical vapor deposition method. When evaluated as cathode for Li-O2 batteries, the binder-free structure showed enhanced ORR/OER activities, thus giving a high rate capability (12690 mAh g(-1) at 200 mA g(-1) and 3999 mAh g(-1) at 2000 mA g(-1)) and outstanding long-term cycling stability (capacity limited 2000 mAh g(-1), 110 cycles at 200 mA g(-1)). The excellent battery performance provides new insights into designing a low-cost and high-efficiency cathode for Li-O2 batteries.

摘要

在这项工作中,对苯二酚树脂被用于在泡沫镍上直接生长碳纳米管。通过一种简单的碳化方法获得了复合材料,该方法避免了使用化学气相沉积法中通常采用的易爆气态碳前驱体。当作为锂氧电池的阴极进行评估时,无粘结剂结构表现出增强的氧还原反应/析氧反应活性,从而具有高倍率性能(在200 mA g(-1) 时为12690 mAh g(-1) ,在2000 mA g(-1) 时为3999 mAh g(-1))以及出色的长期循环稳定性(容量限制为2000 mAh g(-1) ,在200 mA g(-1) 下循环110次)。这种优异的电池性能为设计低成本、高效率的锂氧电池阴极提供了新的思路。

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