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反蛋白石光子晶体作为一种改善光催化的策略:未充分探索的问题。

Inverse Opal Photonic Crystals as a Strategy to Improve Photocatalysis: Underexplored Questions.

作者信息

Curti Mariano, Schneider Jenny, Bahnemann Detlef W, Mendive Cecilia B

机构信息

Departamento de Química, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Mar del Plata , Dean Funes 3350, CP 7600 Mar del Plata, Argentina.

Institut für Technische Chemie, Leibniz Universität Hannover , Callinstraße 3, D-30167 Hannover, Germany.

出版信息

J Phys Chem Lett. 2015 Oct 1;6(19):3903-10. doi: 10.1021/acs.jpclett.5b01353. Epub 2015 Sep 16.

Abstract

The structuring of materials in the form of photonic crystals for photocatalytic applications is a quite new strategy aiming to enhance the performance of the photocatalysts at wavelength ranges where their absorption is poor. It is of particular interest to successfully manufacture an efficient photocatalytic system that could make use of solar light. Thus, the key of the strategy is the "slow photon effect", occurring at the edges of a forbidden band for photons. In this Perspective we have chosen some questions that we consider of relevance and that are well worth being addressed both theoretically and experimentally. It is the aim of this discussion to eventually lead to a more productive use of inverse opals as photonic photocatalytic materials.

摘要

将材料构建成光子晶体形式用于光催化应用是一种相当新的策略,旨在提高光催化剂在其吸收较差的波长范围内的性能。成功制造出一种能够利用太阳光的高效光催化系统尤其令人感兴趣。因此,该策略的关键是“慢光子效应”,它发生在光子禁带的边缘。在这篇综述中,我们选择了一些我们认为相关且非常值得在理论和实验上进行探讨的问题。本次讨论的目的最终是更有效地将反蛋白石用作光子光催化材料。

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