Jeon Sang Koo, Jang Hoon-Sik, Lee Nam Hee, Kwon Oh Heon, Nahm Seung Hoon
J Nanosci Nanotechnol. 2015 Nov;15(11):8711-5. doi: 10.1166/jnn.2015.11483.
Carbon nanofibers (CNFs) are good candidates for nano-system applications because they have the excellent mechanical and the electrical properties. The mechanical and electrical properties of a single CNF were measured. A tensile test and a measurement of the electrical resistance of CNFs during elongation were performed inside a scanning electron microscope. We confirmed that the CNFs used in this experiment consisted of a polycrystalline structure and an amorphous phase by a result of Raman. Additionally, we observed that the crystal structure in nanofibers exhibits brittle fracture behavior and the amorphous phase make them relatively ductile. The elastic moduli of the CNFs were 9.57 to 13.6 GPa in the elastic section. The electrical resistance of the CNFs exhibited unusual behavior during elongation. The electrical resistance of the CNFs exhibited stable resistance increase like as the tensile results in the initial region. But the electrical resistance exhibited generally irregular increase after initial region because of the polycrystalline structure and amorphous phase. The strain sensitivity of the CNFs exhibited a much lower value.
碳纳米纤维(CNFs)是纳米系统应用的理想候选材料,因为它们具有优异的机械性能和电学性能。对单根碳纳米纤维的机械性能和电学性能进行了测量。在扫描电子显微镜内进行了拉伸试验以及碳纳米纤维在拉伸过程中的电阻测量。通过拉曼光谱结果,我们证实本实验中使用的碳纳米纤维由多晶结构和非晶相组成。此外,我们观察到纳米纤维中的晶体结构表现出脆性断裂行为,而非晶相使其具有相对的延展性。在弹性区间,碳纳米纤维的弹性模量为9.57至13.6吉帕。碳纳米纤维的电阻在拉伸过程中表现出异常行为。在初始区域,碳纳米纤维的电阻表现出与拉伸结果类似的稳定电阻增加。但由于多晶结构和非晶相,在初始区域之后电阻通常表现出不规则增加。碳纳米纤维的应变灵敏度值要低得多。