二维锌（II）-三唑骨架内碘诱导的单链-单链转变：含氰基分子的理想探测器
I2-induced SC-SC transformation within two-dimensional Zn(ii)-triazole framework: an ideal detector of cyano-containing molecules.
作者信息
Wang Ying, Yi Jin-Min, Zhang Meng-Yuan, Xu Ping, Zhao Xiao-Jun
机构信息
Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China.
出版信息
Chem Commun (Camb). 2016 Feb 21;52(15):3099-102. doi: 10.1039/c5cc09279e.
A novel interpenetrated 2D + 2D → 2D architechture {[Zn(BTPS)(TPA)]·1.5DMF·H2O}n () has been constructed under solvothermal conditions. Interestingly, I2-induced single-crystal-to-single-crystal transformation to {[Zn(BTPS)(I)(TPA)1.5]·1.5H2O}n () showed a 2D + 1D → 2D array. Luminescent properties indicated that represents the first example of selective recognition toward cyano-containing molecules.
在溶剂热条件下构建了一种新型的互穿二维+二维→二维结构{[Zn(BTPS)(TPA)]·1.5DMF·H₂O}ₙ（）。有趣的是，I₂诱导的单晶到单晶转变为{[Zn(BTPS)(I)(TPA)₁.₅]·1.5H₂O}ₙ（）呈现出二维+一维→二维阵列。发光性质表明，它代表了对含氰基分子选择性识别的首个实例。
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