配体重排诱导的从三维超分子网络到离散八核簇的转变：一种检测铅和铬酸根的优良探测器。
Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb and CrO .
作者信息
Yang Dan-Dan, Liu Yue, Li ShuangShuang, Cheng Lin, Wang Ying, Zhang Ying-Xin, Chen Kai, Gao Yi-Xuan, Ren Peng, Day Gregory S, Wang Ying
机构信息
Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China.
School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen 518055, China.
出版信息
ACS Omega. 2019 Jul 1;4(7):11493-11499. doi: 10.1021/acsomega.9b00680. eCollection 2019 Jul 31.
Abstract
A three-dimensional supramolecular framework containing both left- and right-handed helixes, {[Zn(TTPA)Cl]·1.63HO} (), has been converted to a novel octanuclear cluster containing a metal-organic framework, Zn(ptptp)Cl·4CHOH·2HO (), induced by ligand rearrangement during a solvothermal process. The luminescent properties of indicate that the material can act as a selective probe toward Pb and CrO .
摘要
一种同时包含左旋和右旋螺旋的三维超分子骨架{[Zn(TTPA)Cl]·1.63H₂O} ()，在溶剂热过程中通过配体重排被转化为一种含有金属有机骨架的新型八核簇Zn(ptptp)Cl·4CH₃OH·2H₂O ()。 的发光性质表明该材料可作为对Pb²⁺和Cr₂O₇²⁻的选择性探针。
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