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三维铜（II）-三唑骨架内的SC-SC阴离子辅助连接体交换：一种用于检测硫的发光探针

SC-SC Anion-Assisted Linker Exchange within a Three-Dimensional Cu(II)-Triazole Framework: A Luminescent Probe for S.

作者信息

Wang Ying, Gong Shuang-Shuang, Liu Yue, Cheng Lin, Li Shuang-Shuang, Zhang Ying, Cui Yukun, Liang Chenlu, Tang Li, Ren Peng, Fang Yu, Day Gregory S

机构信息

Tianjin Key Laboratory of Structure and Performance for Functional Molecules; College of Chemistry, Tianjin Normal University, Tianjin 300387, China.

School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen 518055, China.

出版信息

ACS Omega. 2021 Jan 7;6(2):1266-1272. doi: 10.1021/acsomega.0c04676. eCollection 2021 Jan 19.

DOI:10.1021/acsomega.0c04676
PMID:33490785
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7818306/
Abstract

A three-dimensional (3D) binodal 3,5-connected net, {Cu(MTP)(HO)} () with the Schläfli symbol of {3·7}{3·7·8} can be transformed into a two-dimensional (2D) kagóme network with the Schlafli symbol of {3·6·7} in an irreversible single crystal-single crystal (SC-SC) guest-assisted linker exchange process. The product of this SC-SC represents the first luminescent probe for S based on triazole ligand.

摘要

一个具有{3·7}{3·7·8}施莱夫利符号的三维（3D）双节点3,5-连接网络{Cu(MTP)(HO)}（）在不可逆的单晶-单晶（SC-SC）客体辅助配体交换过程中可转变为具有{3·6·7}施莱夫利符号的二维（2D）卡戈梅网络。这种SC-SC过程的产物代表了首个基于三唑配体的硫的发光探针。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b7f/7818306/176e642b8682/ao0c04676_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b7f/7818306/515fbdbf14ba/ao0c04676_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b7f/7818306/ca7039a40936/ao0c04676_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b7f/7818306/4651b04406a4/ao0c04676_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b7f/7818306/0725ae93608d/ao0c04676_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b7f/7818306/176e642b8682/ao0c04676_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b7f/7818306/515fbdbf14ba/ao0c04676_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b7f/7818306/ca7039a40936/ao0c04676_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b7f/7818306/4651b04406a4/ao0c04676_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b7f/7818306/0725ae93608d/ao0c04676_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b7f/7818306/176e642b8682/ao0c04676_0006.jpg

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Cu Cluster with Partial Cu(0) Character: Difference in Electronic Structure from Isostructural Silver Analog.具有部分Cu(0)特性的铜簇：与同结构银类似物的电子结构差异。
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