酚类的不对称去芳构化
Asymmetric dearomatization of phenols.
作者信息
Sun Wangsheng, Li Guofeng, Hong Liang, Wang Rui
机构信息
Key Laboratory of Preclinical Study for New Drugs of Gansu Province, Lanzhou University, Lanzhou, 730000, China.
出版信息
Org Biomol Chem. 2016 Feb 21;14(7):2164-76. doi: 10.1039/c5ob02526e. Epub 2016 Jan 7.
PMID:26740241
Abstract
This review summarizes the recent advances in the field of asymmetric dearomatization of phenols and their applications in the total synthesis of some complex natural products. The dearomatization discussed here includes metal catalysed direct dearomatization, organocatalytic dearomatization and hypervalent iodine mediated dearomatization.
摘要
本综述总结了酚类化合物不对称去芳构化领域的最新进展及其在一些复杂天然产物全合成中的应用。这里讨论的去芳构化包括金属催化的直接去芳构化、有机催化去芳构化和高价碘介导的去芳构化。
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