Burés Jordi
Imperial College London, Department of Chemistry, Exhibition Road, South Kensington, SW7 2AZ, London, UK.
Angew Chem Int Ed Engl. 2016 Feb 5;55(6):2028-31. doi: 10.1002/anie.201508983. Epub 2016 Jan 8.
A graphical analysis to elucidate the order in catalyst is presented. This analysis uses a normalized time scale, t [cat]T (n) , to adjust entire reaction profiles constructed with concentration data. The method is fast and simple to perform because it directly uses the concentration data, therefore avoiding the data handling that is usually required to extract rates. Compared to methods that use rates, the normalized time scale analysis requires fewer experiments and minimizes the effects of experimental errors by using information on the entire reaction profile.
本文提出了一种用于阐明催化剂顺序的图形分析方法。该分析使用归一化时间尺度t [cat]T (n) 来调整由浓度数据构建的整个反应曲线。该方法快速且易于执行,因为它直接使用浓度数据,因此避免了通常提取速率所需的数据处理。与使用速率的方法相比,归一化时间尺度分析所需的实验较少,并且通过使用整个反应曲线的信息将实验误差的影响降至最低。