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V2O5/聚吲哚与活性炭布的竹节状复合材料用作全固态柔性非对称超级电容器的电极

Bamboo-like Composites of V2O5/Polyindole and Activated Carbon Cloth as Electrodes for All-Solid-State Flexible Asymmetric Supercapacitors.

作者信息

Zhou Xi, Chen Qiang, Wang Anqi, Xu Jian, Wu Shishan, Shen Jian

机构信息

School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210093, People's Republic of China.

出版信息

ACS Appl Mater Interfaces. 2016 Feb 17;8(6):3776-83. doi: 10.1021/acsami.5b10196. Epub 2016 Feb 2.

Abstract

A bamboo-like nanomaterial composed of V2O5/polyindole (V2O5/PIn) decorated onto the activated carbon cloth was fabricated for supercapacitors. The PIn could effectively enhance the electronic conductivity and prevent the dissolution of vanadium. And the activation of carbon cloth with functional groups is conducive to anchoring the V2O5 and improving surface area, which results in an enhancement of electrochemical performance and leads to a high specific capacitance of 535.5 F/g. Moreover, an asymmetric flexible supercapacitor based on V2O5/PIn@activate carbon cloth and reduced graphene oxide (rGO)@activate carbon cloth exhibits a high energy density (38.7 W h/kg) at a power density of 900 W/kg and good cyclic stability (capacitance retention of 91.1% after 5000 cycles). And the prepared device is shown to power the light-emitting diode bulbs efficiently.

摘要

制备了一种由负载在活性炭布上的V2O5/聚吲哚(V2O5/PIn)组成的竹节状纳米材料用于超级电容器。聚吲哚可以有效提高电子导电性并防止钒溶解。用官能团对活性炭布进行活化有利于锚定V2O5并增加表面积,从而提高电化学性能,使比电容高达535.5 F/g。此外,基于V2O5/PIn@活性炭布和还原氧化石墨烯(rGO)@活性炭布的非对称柔性超级电容器在功率密度为900 W/kg时具有高能量密度(38.7 W h/kg)和良好的循环稳定性(5000次循环后电容保持率为91.1%)。所制备的器件能够有效地为发光二极管灯泡供电。

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