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用于通用净水的淀粉样蛋白-碳杂化膜。

Amyloid-carbon hybrid membranes for universal water purification.

机构信息

Department of Health Sciences and Technology, ETH Zurich, Schmelzbergstrasse 9, Zurich 8092, Switzerland.

出版信息

Nat Nanotechnol. 2016 Apr;11(4):365-71. doi: 10.1038/nnano.2015.310. Epub 2016 Jan 25.

Abstract

Industrial development, energy production and mining have led to dramatically increased levels of environmental pollutants such as heavy metal ions, metal cyanides and nuclear waste. Current technologies for purifying contaminated waters are typically expensive and ion specific, and there is therefore a significant need for new approaches. Here, we report inexpensive hybrid membranes made from protein amyloid fibrils and activated porous carbon that can be used to remove heavy metal ions and radioactive waste from water. During filtration, the concentration of heavy metal ions drops by three to five orders of magnitude per passage and the process can be repeated numerous times. Notably, their efficiency remains unaltered when filtering several ions simultaneously. The performance of the membrane is enabled by the ability of the amyloids to selectively absorb heavy metal pollutants from solutions. We also show that our membranes can be used to recycle valuable heavy metal contaminants by thermally reducing ions trapped in saturated membranes, leading to the creation of elemental metal nanoparticles and films.

摘要

工业发展、能源生产和采矿导致环境污染物如重金属离子、金属氰化物和核废料的水平显著增加。目前净化受污染水的技术通常昂贵且针对特定离子,因此需要新的方法。在这里,我们报告了由蛋白淀粉样纤维和活化多孔碳制成的廉价混合膜,可用于从水中去除重金属离子和放射性废物。在过滤过程中,重金属离子的浓度每通过一次就降低三个到五个数量级,并且该过程可以重复多次。值得注意的是,当同时过滤几种离子时,其效率保持不变。该膜的性能是由淀粉样蛋白从溶液中选择性吸附重金属污染物的能力所决定的。我们还表明,我们的膜可以通过热还原饱和膜中捕获的离子来回收有价值的重金属污染物,从而产生元素金属纳米粒子和薄膜。

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