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膨胀石墨纳米流体的粘塑性行为证据。

Evidence of viscoplastic behavior of exfoliated graphite nanofluids.

作者信息

Hermida-Merino Carolina, Pérez-Rodríguez Martín, Piñeiro Manuel M, Pastoriza-Gallego María José

机构信息

Departmento de Física Aplicada, Universidade de Vigo, Spain.

出版信息

Soft Matter. 2016 Feb 28;12(8):2264-75. doi: 10.1039/c5sm02932e.

Abstract

The rheological behavior of ethylene glycol-based nanofluids containing exfoliated graphite nanoplatelets has been carried out using a cone-plate Physica MCR rheometer. Initial experiments based on flow curves were carried out, the flow curves were based on the controlled shear stress model, these tests show that the studied nanofluids present non-Newtonian shear thinning behavior with yield stress. Furthermore, linear viscoelastic experiments were conducted in order to determine the viscoelastic behavior: using strain sweep and frequency sweep tests the storage and loss modulus were determined. The fractal dimension (Df) was estimated from the suspension static yield-stress and volume fraction (ϕ) dependence, and was determined to be Df = 2.36, a value consistent with a process of aggregation of RLCA type (reaction limited cluster aggregation). This value is unusual if compared with other nanofluids, and can be regarded as a result of the bidimensionality of the suspended nanoplatelets. Finally, creep-recovery tests and mechanical models confirm the viscoplastic nature of our nanofluids, a feature never shown so far for this type of systems, increasing the solid-like character in the range of concentrations studied if compared with other nanofluids reported in the literature. This is a result of the combination of a remarkable internal structure and strong interactions, which evidence an unexpected behaviour sharing many solid-like features.

摘要

使用锥板Physica MCR流变仪对含有片状石墨纳米片的乙二醇基纳米流体的流变行为进行了研究。基于流动曲线进行了初始实验,流动曲线基于控制剪切应力模型,这些测试表明所研究的纳米流体呈现具有屈服应力的非牛顿剪切变稀行为。此外,进行了线性粘弹性实验以确定粘弹性行为:通过应变扫描和频率扫描测试确定了储能模量和损耗模量。从悬浮液的静态屈服应力和体积分数(ϕ)依赖性估计分形维数(Df),并确定为Df = 2.36,该值与RLCA类型(反应限制簇聚)的聚集过程一致。与其他纳米流体相比,该值不同寻常,可视为悬浮纳米片二维性的结果。最后,蠕变恢复测试和力学模型证实了我们的纳米流体的粘塑性性质,这是这类系统迄今为止从未表现出的特征,与文献中报道的其他纳米流体相比,在所研究的浓度范围内增加了类固体特性。这是显著的内部结构和强相互作用相结合的结果,这证明了一种具有许多类固体特征的意外行为。

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