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开发一种新的β Ti 合金,具有低模量和良好的塑性,可作为植入物材料。

Development of a new β Ti alloy with low modulus and favorable plasticity for implant material.

机构信息

College of Equipment Manufacture, Hebei University of Engineering, Handan 056038, Hebei, China.

College of Equipment Manufacture, Hebei University of Engineering, Handan 056038, Hebei, China.

出版信息

Mater Sci Eng C Mater Biol Appl. 2016 Apr 1;61:338-43. doi: 10.1016/j.msec.2015.12.076. Epub 2015 Dec 30.

Abstract

One of the most important development directions of the Ti and its alloys is the applications in medical field. Development of new Ti alloys with low elastic modulus and/or favorable biocompatibility plays an important role for promoting its application in medical field. In this work, a new β Ti alloy (Ti-31Nb-6Zr-5Mo, wt.%) was designed for implant material using d-electron alloy design method. Microstructure and tensile properties of the designed alloy after hot rolling (HR) and solution followed by aging treatments (SA) were investigated. Results show that the designed alloy is composed of single β phase. However, microstructural analysis shows that the β phase in the designed alloy separates into Nb-rich and Nb-poor phase regions. The Nb-rich regions in HR specimen are typical elongated fiber texture, but are equiaxed particles with several micrometers in SA specimen. Tensile results show that the designed alloy has low Young's modulus of 44 GPa for HR specimen and 48 GPa for SA specimen which are very close to the extreme of Young's modulus of bulk titanium alloys. At the same time, the designed alloy has favorable plasticity in term of elongation of 26.7% for HR specimen and 20.6% for SA specimen, and appropriate tensile strength over 700 MPa. In short, the designed alloy has low elastic modulus close to that of bone and favorable plasticity and strength which can be a potential candidate for hard tissue replacements.

摘要

钛及钛合金最重要的发展方向之一是在医学领域的应用。开发具有低弹性模量和/或良好生物相容性的新型钛合金对于促进其在医学领域的应用起着重要作用。本工作采用 d 电子合金设计方法,设计了一种新型β钛合金(Ti-31Nb-6Zr-5Mo,wt.%)作为植入材料。研究了热轧(HR)和固溶时效处理(SA)后设计合金的组织和拉伸性能。结果表明,设计合金由单相β组成。然而,微观结构分析表明,设计合金中的β相分离成富铌和贫铌相区。HR 试样中的富铌区具有典型的长纤维织构,但在 SA 试样中为几微米的等轴颗粒。拉伸结果表明,设计合金的 HR 试样的杨氏模量低至 44 GPa,SA 试样的杨氏模量低至 48 GPa,非常接近体钛合金杨氏模量的极值。同时,设计合金具有良好的塑性,HR 试样的伸长率为 26.7%,SA 试样的伸长率为 20.6%,拉伸强度超过 700 MPa。总之,设计合金具有接近骨骼的低弹性模量和良好的塑性和强度,可作为硬组织替代物的潜在候选材料。

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