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用于环境修复的吨级(10²⁰ 个单位)Fe(0) 纳米马达

Fe(0) Nanomotors in Ton Quantities (10(20) Units) for Environmental Remediation.

作者信息

Teo Wei Zhe, Zboril Radek, Medrik Ivo, Pumera Martin

机构信息

Division of Chemistry and Biological Chemistry, School of Physical and Chemical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore, 637371, Singapore.

Regional Centre of Advanced Technologies and Materials, Departments of Physical Chemistry and Experimental Physics, Faculty of Science, Palacký University, 17. listopadu 1192/12, 771 46, Olomouc, Czech Republic.

出版信息

Chemistry. 2016 Mar 24;22(14):4789-93. doi: 10.1002/chem.201504912. Epub 2016 Feb 4.

Abstract

Despite demonstrating potential for environmental remediation and biomedical applications, the practical environmental applications of autonomous self-propelled micro-/nanorobots have been limited by the inability to fabricate these devices in large (kilograms/tons) quantities. In view of the demand for large-scale environmental remediation by micro-/nanomotors, which are easily synthesized and powered by nontoxic fuel, we have developed bubble-propelled Fe(0) Janus nanomotors by a facile thermally induced solid-state procedure and investigated their potential as decontamination agents of pollutants. These Fe(0) Janus nanomotors, stabilized by an ultrathin iron oxide shell, were fuelled by their decomposition in citric acid, leading to the asymmetric bubble propulsion. The degradation of azo-dyes was dramatically increased in the presence of moving self-propelled Fe(0) nanomotors, which acted as reducing agents. Such enhanced pollutant decomposition triggered by biocompatible Fe(0) (nanoscale zero-valent iron motors), which can be handled in the air and fabricated in ton quantities for low cost, will revolutionize the way that environmental remediation is carried out.

摘要

尽管自主自推进微纳机器人在环境修复和生物医学应用方面展现出潜力,但其实际环境应用受到无法大量(千克/吨级)制造这些装置的限制。鉴于对由无毒燃料轻松合成并驱动的微纳马达进行大规模环境修复的需求,我们通过简便的热诱导固态方法开发了气泡推进的Fe(0) 双面纳米马达,并研究了它们作为污染物净化剂的潜力。这些由超薄氧化铁壳稳定的Fe(0) 双面纳米马达,通过在柠檬酸中的分解作为燃料,从而实现不对称气泡推进。在移动的自推进Fe(0) 纳米马达(作为还原剂)存在的情况下,偶氮染料的降解显著增加。这种由生物相容性Fe(0)(纳米级零价铁马达)引发的污染物分解增强,其可在空气中处理且能以吨级低成本制造,将彻底改变环境修复的实施方式。

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